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Reversible Cross-Linking of Aliphatic Polyamides Bearing Thermo- and Photoresponsive Cinnamoyl Moieties

dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierUniv Liege, Ctr Educ & Res Macromol
dc.contributor.authorTUNC, Deniz
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorLE COZ, Cédric
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierUniv Liege, Ctr Educ & Res Macromol
dc.contributor.authorALEXANDRE, Michael
hal.structure.identifierBASF SE, Adv Mat & Syst Res
dc.contributor.authorDESBOIS, Philippe
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierUniv Liege, Ctr Educ & Res Macromol
dc.contributor.authorPHILIPPE, Lecomte
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorCARLOTTI, Stéphane
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2014
dc.identifier.issn0024-9297
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20221
dc.description.abstractEnPhotosensitive polymers have gained strong attention in development of different polymeric systems for diverse applications. Particular attention is paid to polymers with cinnamoyl groups either in polymer backbone or in pendent position owing to their excellent photoreactivity and thermoreactivity upon UV light irradiation or heating. This work aims at synthesizing a novel photo- and thermosensitive aliphatic polyamide by anionic ring-opening copolymerization of epsilon-caprolactam and a-cinnamoylamido-epsilon-caprolactam. The photochemical reversible cross-linking of solutions and thermal cross-linking of spin-coated films made up of these new cinnamoyl-functionalized polyamides were monitored by UV-vis spectroscopy. These aliphatic polyamide copolymers were characterized by magic angle spinning solid-state NMR, and their thermal behaviors were studied by thermogravimetric analysis, differential scanning calorimetry, and dynamic mechanical analysis.
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.subject.enBEHAVIOR
dc.subject.enDESIGN
dc.subject.enACID
dc.subject.enLIQUID-CRYSTALLINE POLYMERS
dc.subject.enSHAPE-MEMORY
dc.subject.enFILMS
dc.subject.enPOLYMERIZATION
dc.subject.enDIMERIZATION
dc.subject.enALIGNMENT
dc.title.enReversible Cross-Linking of Aliphatic Polyamides Bearing Thermo- and Photoresponsive Cinnamoyl Moieties
dc.typeArticle de revue
dc.identifier.doi10.1021/ma502083p
dc.subject.halChimie/Polymères
bordeaux.journalMacromolecules
bordeaux.page8247-8254
bordeaux.volume47
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue23
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-01369574
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01369574v1
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