Anisotropic Lithium Ion Conductivity in Single-Ion Diblock Copolymer Electrolyte Thin Films
| dc.rights.license | open | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | AISSOU, Karim | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | MUMTAZ, Muhammad | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | USLUER, Özlem | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | PECASTAINGS, Gilles | |
| hal.structure.identifier | Univ Groningen, Zernike Inst Adv Mat, Macromol Chem & New Polym Mat | |
| dc.contributor.author | PORTALE, Giuseppe | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | FLEURY, Guillaume | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | CLOUTET, Eric
IDREF: 151048681 | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | HADZIIOANNOU, Georges | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2016 | |
| dc.identifier.issn | 1022-1336 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20218 | |
| dc.description.abstractEn | Well-defined single-ion diblock copolymers consisting of a Li-ion conductive poly(styrenesulfonyllithium(trifluoromethylsulfonyl)imide) (PSLiTFSI) block associated with a glassy polystyrene (PS) block have been synthesized via reversible addition fragmentation chain transfer polymerization. Conductivity anisotropy ratio up to 1000 has been achieved from PS-b-PSLiTFSI thin films by comparing Li-ion conductivities of out-of-plane (aligned) and in-plane (antialigned) cylinder morphologies at 40 degrees C. Blending of PS-b-PSLiTFSI thin films with poly(ethylene oxide) homopolymer (hPEO) enables a substantial improvement of Li-ion transport within aligned cylindrical domains, since hPEO, preferentially located in PSLiTFSI domains, is an excellent lithium-solvating material. Results are also compared with unblended and blended PSLiTFSI homopolymer (hPSLiTFSI) homologues, which reveals that ionic conductivity is improved when thin films are nanostructured. | |
| dc.language.iso | en | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.subject.en | MOLECULAR-WEIGHT | |
| dc.subject.en | BLOCK-COPOLYMER | |
| dc.subject.en | thin films | |
| dc.subject.en | ORDER | |
| dc.subject.en | BATTERIES | |
| dc.subject.en | block copolymers | |
| dc.subject.en | ionic conductivity | |
| dc.subject.en | RAFT polymerization | |
| dc.title.en | Anisotropic Lithium Ion Conductivity in Single-Ion Diblock Copolymer Electrolyte Thin Films | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1002/marc.201500562 | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | Macromolecular Rapid Communications | |
| bordeaux.page | 221-226 | |
| bordeaux.volume | 37 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 3 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01369626 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01369626v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Macromolecular%20Rapid%20Communications&rft.date=2016&rft.volume=37&rft.issue=3&rft.spage=221-226&rft.epage=221-226&rft.eissn=1022-1336&rft.issn=1022-1336&rft.au=AISSOU,%20Karim&MUMTAZ,%20Muhammad&USLUER,%20%C3%96zlem&PECASTAINGS,%20Gilles&PORTALE,%20Giuseppe&rft.genre=article |
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