Post-polymerization modification and organocatalysis using reactive statistical poly(ionic liquid)-based copolymers
| dc.rights.license | open | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Univ Basque Country UPV EHU, Joxe Mari Korta Ctr, POLYMAT | |
| dc.contributor.author | COUPILLAUD, Paul | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | VIGNOLLE, Joan | |
| hal.structure.identifier | Univ Basque Country UPV EHU, Joxe Mari Korta Ctr, POLYMAT | |
| dc.contributor.author | MECERREYES, David | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | TATON, Daniel | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2014 | |
| dc.identifier.issn | 0032-3861 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20196 | |
| dc.description.abstractEn | Copoly(ionic liquid)s (coPILs) based on poly(styrene)-co-poly(4-vinylbenzylbutylimidazolium) with different anions (Cl- and HCO3-), denoted as PS-co-PVBnBuImCl 1 and PS-co-PVBnBuImHCO(3) 2, were used as reactive polymers for the purpose of post-polymerization modification and organic catalysis. While coPIL 1 could be derived into the corresponding poly(N-heterocyclic carbene)-silver transition metal complex referred to as poly(NHC-Ag) by a simple deprotonation/metallation sequence utilizing Ag2O, coPIL 2 was found to quantitatively react with various electrophiles, including CS2, isothiocyanate and transition metals (based on Pd and Au) upon formal loss of "H2CO3, affording the post-functionalized poly(NHC-CS2), poly(NHC-isothiocyanate) and poly(NHC-Met) (Met = Au, Pd) copolymers. The catalytic activity of both coPILs 1 and 2 was also examined in cyclic carbonate formation by reaction between CO2 and propylene oxide and in the benzoin condensation, respectively. (C) 2014 Elsevier Ltd. All rights reserved. | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.subject.en | Poly(ionic liquid) | |
| dc.subject.en | Post-polymerization modification | |
| dc.subject.en | Catalysis | |
| dc.subject.en | N-HETEROCYCLIC CARBENES | |
| dc.subject.en | IONIC LIQUIDS | |
| dc.subject.en | HYDROGEN CARBONATES | |
| dc.subject.en | STRUCTURAL-CHARACTERIZATION | |
| dc.subject.en | MECHANISTIC INSIGHT | |
| dc.subject.en | CYCLIC CARBONATES | |
| dc.subject.en | COMPLEXES | |
| dc.subject.en | CATALYSTS | |
| dc.subject.en | POLYMERS | |
| dc.subject.en | EPOXIDES | |
| dc.title.en | Post-polymerization modification and organocatalysis using reactive statistical poly(ionic liquid)-based copolymers | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/j.polymer.2014.02.043 | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | Polymer | |
| bordeaux.page | 3404-3414 SI | |
| bordeaux.volume | 55 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 16 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01373014 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01373014v1 | |
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