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dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierDepartment of Chemistry [Waterloo]
dc.contributor.authorNEQAL, Mehdi
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorPICHAVANT, Loïc
hal.structure.identifierDepartment of Chemistry [Waterloo]
dc.contributor.authorGAUTHIER, Mario
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorHÉROGUEZ, Valérie
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2016
dc.identifier.issn0927-7757
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20156
dc.description.abstractEnDispersion Ring-Opening Metathesis Polymerization (ROMP) of norbornene (Nb) in the presence of a hydrophilic alpha-norbornenyl-polyglycidol macromonomer is a powerful method to obtain stabilized polymeric core-shell nanoparticles (NPs). Thanks to their high hydroxyl functionality content, one for every structural unit along the chain, the polyglycidol-based NPs can be viewed as plurifunctional platforms for the attachment of active molecules. The synthesis of polyglycidol macromonomers by anionic polymerization and their copolymerization with norbornene to give the NPs is described in the first part of this paper. In the second part, we take advantage of the presence of the hydroxyl groups to synthesize NPs with a high functionalization capacity. Dodecylamine, a primary amine known for its biocidal properties was selected as a model molecule and conjugated to the polyglycidol chains using a pH-sensitive imine bond. (C) 2016 Elsevier B.V. All rights reserved.
dc.language.isoen
dc.publisherElsevier
dc.subject.enFunctionalized nanoparticles
dc.subject.enROMP
dc.subject.enDispersion polymerization
dc.subject.enMacromonomers
dc.subject.enPolyglycidol
dc.subject.enDodecylamine
dc.subject.enCONJUGATE NANOPARTICLES
dc.subject.enPOLY(ETHYLENE OXIDE)
dc.subject.enBLOCK-COPOLYMERS
dc.subject.enDELIVERY
dc.subject.enPOLYMERS
dc.subject.enGLYCIDOL
dc.subject.enSHELL
dc.subject.enCORE
dc.title.enPlurifunctional polyglycidol-based particles prepared by Dispersion Ring-Opening Metathesis Polymerization
dc.typeArticle de revue
dc.identifier.doi10.1016/j.colsurfa.2016.04.056
dc.subject.halChimie/Polymères
bordeaux.journalColloids and Surfaces A: Physicochemical and Engineering Aspects
bordeaux.page254-262
bordeaux.volume510
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issuesi
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-01416213
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01416213v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Colloids%20and%20Surfaces%20A:%20Physicochemical%20and%20Engineering%20Aspects&rft.date=2016&rft.volume=510&rft.issue=si&rft.spage=254-262&rft.epage=254-262&rft.eissn=0927-7757&rft.issn=0927-7757&rft.au=NEQAL,%20Mehdi&PICHAVANT,%20Lo%C3%AFc&GAUTHIER,%20Mario&H%C3%89ROGUEZ,%20Val%C3%A9rie&rft.genre=article


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