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dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorSAVE, Maud
dc.contributor.authorSOUM, A.
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2002
dc.identifier.issn1022-1352
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20108
dc.description.abstractEnThe mechanism of ring-opening polymerization of some lactones and lactide initiated by lanthanum isopropoxide has been comprehensively investigated. NMR and viscosity analyses demonstrated that three active polymer chains grow per lanthanum atom and that. depending on the coordinating ability of the monomer, propagation proceeds on aggregated or unaggregated active species. It is also demonstrated that inter- and intramolecular side reactions are limited and that lanthanum-based initiator selectivity in ring-opening polymerization is analogous to that of aluminum ones.
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.title.enControlled ring-opening polymerization of lactones and lactide initiated by lanthanum isopropoxide, 2a: Mechanistic studies
dc.typeArticle de revue
dc.identifier.doi10.1002/macp.200290043
dc.subject.halChimie/Polymères
bordeaux.journalMacromolecular Chemistry and Physics
bordeaux.page2591-2603
bordeaux.volume203
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue18
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-01563822
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01563822v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Macromolecular%20Chemistry%20and%20Physics&rft.date=2002&rft.volume=203&rft.issue=18&rft.spage=2591-2603&rft.epage=2591-2603&rft.eissn=1022-1352&rft.issn=1022-1352&rft.au=SAVE,%20Maud&SOUM,%20A.&rft.genre=article


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