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Vapor phase synthesized poly(3,4-ethylenedioxythiophene)-trifluoromethanesulfonate as a transparent conductor material

dc.rights.licenseopen
dc.contributor.authorBROOKE, Robert
dc.contributor.authorFRANCO-GONZALEZ, Juan Felipe
dc.contributor.authorWIJERATNE, Kosala
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorPAVLOPOULOU, Eleni
dc.contributor.authorGALLIANI, Daniela
dc.contributor.authorLIU, Xianjie
dc.contributor.authorVALIOLLAHI, Roudabeh
dc.contributor.authorZOZOULENKO, Igor
hal.structure.identifierDepartment of Science and Technology [Linköping]
dc.contributor.authorCRISPIN, Xavier
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2018
dc.identifier.issn2050-7488
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/19954
dc.description.abstractEnInorganic transparent conductive oxides have dominated the market as transparent electrodes due to theirhigh conductivity and transparency. Here, we report the fabrication and optimization of the synthesis ofpoly(3,4-ethylenedioxythiophene) trifluoromethanesulfonate via vapor phase polymerization for thepotential replacement of such inorganic materials. The parameters and conditions of the polymerizationwere investigated and an electrical conductivity of 3800 S cm1 and 4500 S cm1 after acid treatmentwere obtained while maintaining an absorbance similar to that of commercial indium tin oxide. Thisincrease in electrical conductivity was rationalized experimentally and theoretically to an increase in theoxidation level and a higher order of crystallinity which does not disrupt the p–p stacking of PEDOT chains.
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.subject.enTransparent Conductors
dc.subject.enPEDOT film
dc.subject.enVapor phase polymerization
dc.title.enVapor phase synthesized poly(3,4-ethylenedioxythiophene)-trifluoromethanesulfonate as a transparent conductor material
dc.typeArticle de revue
dc.identifier.doi10.1039/c8ta04744h
dc.subject.halChimie/Polymères
bordeaux.journalJournal of Materials Chemistry A
bordeaux.page21304 - 21312
bordeaux.volume6
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue43
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-01933477
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01933477v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20Materials%20Chemistry%20A&rft.date=2018&rft.volume=6&rft.issue=43&rft.spage=21304%20-%2021312&rft.epage=21304%20-%2021312&rft.eissn=2050-7488&rft.issn=2050-7488&rft.au=BROOKE,%20Robert&FRANCO-GONZALEZ,%20Juan%20Felipe&WIJERATNE,%20Kosala&PAVLOPOULOU,%20Eleni&GALLIANI,%20Daniela&rft.genre=article


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