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Photo-polymerization induced polymersome rupture

dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 3 LCPO : Polymer Self-Assembly & Life Sciences
dc.contributor.authorLARNAUDIE, Sophie
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 3 LCPO : Polymer Self-Assembly & Life Sciences
dc.contributor.authorPEYRET, Ariane
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 3 LCPO : Polymer Self-Assembly & Life Sciences
dc.contributor.authorBEAUTÉ, Louis
hal.structure.identifierLaboratoire Photonique, Numérique et Nanosciences [LP2N]
dc.contributor.authorNASSOY, Pierre
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 3 LCPO : Polymer Self-Assembly & Life Sciences
dc.contributor.authorLECOMMANDOUX, Sebastien
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2019
dc.identifier.issn0743-7463
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/19855
dc.description.abstractEnPoly(butadiene)-b-poly(ethylene oxide) (PBut2.5-b-PEO1.3) giant polymersomes were prepared using an emulsion-centrifugation method. The impact of a fast decrease of the osmotic pressure inside the lumen of giant PBut-b-PEO vesicles was studied by confocal microscopy. This osmotic imbalance was created by performing the photo-induced polymerization of acrylamide inside these giant polymersomes, mimicking cell-like confinement. Experimental conditions (irradiation time, relative concentration of monomer and photo-initiator) were optimized to induce the fastest and highest osmotic pressure difference in bulk solution. When confined inside polymersomes with low permeability membrane made of PBut-b-PEO copolymers, this hyper-osmotic shock induced a fast disruption of the membrane and polymersome burst. These findings, complementary to hypo-osmotic shock approaches previously reported, are demonstrating the versatility and relevance of controlling and modulating osmotic pressure imbalance in self-assembled artificial cell systems and protocells.
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.title.enPhoto-polymerization induced polymersome rupture
dc.typeArticle de revue
dc.identifier.doi10.1021/acs.langmuir.9b01463
dc.subject.halChimie/Polymères
dc.subject.halChimie/Matériaux
dc.subject.halPhysique [physics]/Matière Condensée [cond-mat]/Matière Molle [cond-mat.soft]
bordeaux.journalLangmuir
bordeaux.page8398-8403
bordeaux.volume35
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue25
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-02151738
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-02151738v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Langmuir&rft.date=2019&rft.volume=35&rft.issue=25&rft.spage=8398-8403&rft.epage=8398-8403&rft.eissn=0743-7463&rft.issn=0743-7463&rft.au=LARNAUDIE,%20Sophie&PEYRET,%20Ariane&BEAUT%C3%89,%20Louis&NASSOY,%20Pierre&LECOMMANDOUX,%20Sebastien&rft.genre=article


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