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Divinylglycol, a Glycerol-Based Monomer: Valorization, Properties, and Applications

dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
hal.structure.identifierTeam 2 LCPO : Biopolymers & Bio-sourced Polymers
dc.contributor.authorBONNOT, Lea
hal.structure.identifierSynthèse et réactivité des substances naturelles [SRSN]
dc.contributor.authorLEN, Christophe
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 2 LCPO : Biopolymers & Bio-sourced Polymers
dc.contributor.authorGRAU, Etienne
IDREF: 187909261
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 2 LCPO : Biopolymers & Bio-sourced Polymers
dc.contributor.authorCRAMAIL, Henri
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2018
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/19800
dc.description.abstractEnIn the context of the development of bio-refineries, glycerol and its derivatives are co-products of the oleochemistry for which new valorization routes must be found. In this study, the polymerizability of divinylglycol (DVG), a symmetrical C-6 glycerol derivative which bears a vicinal diol and two vinyl functions was studied. The reactivity of the hydroxyl and vinyl functions of DVG through polycondensation and polyaddition reactions was investigated. In a first step, the synthesis of polyesters was carried out by reaction of DVG with various biosourced diesters. In a second route, DVG was polymerized through its vinyl functions by ADMET and thiol-ene addition. Finally, three-dimensional epoxy-amine networks were prepared from a series of diamines and bis-epoxidized DVG, the latter being prepared by oxidation of the DVG double bonds. These different polymerization reactions showed that DVG double bonds were more reactive than the alcohol ones and that a panel of original polymers could be obtained from this bio-sourced synthon.
dc.language.isoen
dc.source.titleGreen Polymer Chemistry: New Products, Processes, and Applications
dc.title.enDivinylglycol, a Glycerol-Based Monomer: Valorization, Properties, and Applications
dc.typeChapitre d'ouvrage
dc.identifier.doi10.1021/bk-2018-1310.ch019
dc.subject.halChimie/Polymères
dc.subject.halChimie/Matériaux
dc.subject.halPhysique [physics]/Matière Condensée [cond-mat]/Science des matériaux [cond-mat.mtrl-sci]
dc.identifier.arxiv1911.08909
bordeaux.page299-330
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
hal.identifierhal-02367169
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-02367169v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.btitle=Green%20Polymer%20Chemistry:%20New%20Products,%20Processes,%20and%20Applications&rft.date=2018&rft.spage=299-330&rft.epage=299-330&rft.au=BONNOT,%20Lea&LEN,%20Christophe&GRAU,%20Etienne&CRAMAIL,%20Henri&rft.genre=unknown


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