Homo- and Copolymerizations of (Meth)Acrylates with Olefins (Styrene, Ethylene) Using Neutral Nickel Complexes: A Dual Radical/Catalytic Pathway
Langue
en
Article de revue
Ce document a été publié dans
Macromolecules. 2011, vol. 44, n° 9, p. 3293-3301
American Chemical Society
Résumé en anglais
Nickel complexes [(X,O)NiR(PPh(3))] (X = N or P), designed for the polymerization of ethylene, were found to be efficient for the homo- and copolymerization of butylacrylate (BuA), methylmethacrylate (MMA), and styrene. ...Lire la suite >
Mots clés en anglais
HOMOPOLYMERIZATION
ACRYLATE
PALLADIUM COMPLEXES
POLAR VINYL MONOMERS
METHYL-METHACRYLATE
POLYMERIZATION CATALYSTS
INSERTION POLYMERIZATION
NI(ACAC)(2)-METHYLALUMINOXANE CATALYST
RADICAL COPOLYMERIZATION
MECHANISTIC INSIGHTS