From Lignin-derived Aromatic Compounds to Novel Biobased Polymers
Language
en
Article de revue
This item was published in
Macromolecular Rapid Communications. 2016, vol. 37, n° 1, p. 9-28
Wiley-VCH Verlag
English Abstract
Nowadays, the synthesis of (semi) aromatic polymers from lignin derivatives is of major interest, as aromatic compounds are key intermediates in the manufacture of polymers and lignin is the main source of aromatic biobased ...Read more >
Nowadays, the synthesis of (semi) aromatic polymers from lignin derivatives is of major interest, as aromatic compounds are key intermediates in the manufacture of polymers and lignin is the main source of aromatic biobased substrates. Phenols with a variety of chemical structures can be obtained from lignin deconstruction; among them, vanillin and ferulic acid are the main ones. Depending on the phenol substrates, different chemical modifications and polymerization pathways are developed, leading to (semi) aromatic polymers covering a wide range of thermomechanical properties. This review discusses the synthesis and properties of thermosets (vinyl ester resins, cyanate ester, epoxy, and benzoxazine resins) and thermoplastic polymers (polyesters, polyanhydrides, Schiff base polymers, polyacetals, polyoxalates, polycarbonates, acrylate polymers) prepared from vanillin, ferulic acid, guaiacol, syringaldehyde, or 4-hydroxybenzoic acid.Read less <
English Keywords
THERMOTROPIC POLYESTERS
SUSTAINABLE POLYMERS
RENEWABLE RESOURCES
TEREPHTHALATE POLYESTERS
lignin
polymers
thermosets
vanillin
P-HYDROXYBENZOIC ACID
VANILLIC ACID
THERMAL-PROPERTIES
FERULIC ACID
2 5-FURANDICARBOXYLIC ACID
CONTROLLED POLYMERIZATION
Origin
Hal imported