Polynorbornene latex synthesis by UV-triggered Ring-Opening Metathesis Polymerization in miniemulsion
| dc.rights.license | open | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | PICHAVANT, Loïc | |
| hal.structure.identifier | Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM] | |
| dc.contributor.author | LACROIX-DESMAZES, Patrick | |
| hal.structure.identifier | Departement de Photochimie Générale | |
| hal.structure.identifier | Institut de Science des Matériaux de Mulhouse [IS2M] | |
| dc.contributor.author | CHEMTOB, Abraham | |
| hal.structure.identifier | Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM] | |
| dc.contributor.author | PINAUD, Julien | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | HÉROGUEZ, Valérie | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2020 | |
| dc.identifier.issn | 0032-3861 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/19729 | |
| dc.description.abstractEn | An innovative route based on a novel photo-latent ROMP initiator has been explored to synthesize polynorbornene latex particles in miniemulsion. Operation conditions were strongly improved by the use of an annular LED photo-reactor, increasing the uniformity of radiation distribution and enabling to control atmosphere and stirring throughout irradiation. Several parameters (droplet size, irradiance, pre-catalyst structure) were studied in order to improve the monomer conversion profiles, which eventually led to the production of latex with high norbornene conversion (>90%) and 10% solids content. Particular attention was paid to the polymer microstructure, which was found to be highly dependent on the type of initiation mechanism. | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.subject.en | Ring-Opening Metathesis Polymerization | |
| dc.subject.en | polymerization in miniemulsion | |
| dc.subject.en | latex | |
| dc.subject.en | Photo-latent initiator | |
| dc.title.en | Polynorbornene latex synthesis by UV-triggered Ring-Opening Metathesis Polymerization in miniemulsion | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/j.polymer.2020.122200 | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | Polymer | |
| bordeaux.page | 122200 | |
| bordeaux.volume | 190 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-02467679 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-02467679v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Polymer&rft.date=2020&rft.volume=190&rft.spage=122200&rft.epage=122200&rft.eissn=0032-3861&rft.issn=0032-3861&rft.au=PICHAVANT,%20Lo%C3%AFc&LACROIX-DESMAZES,%20Patrick&CHEMTOB,%20Abraham&PINAUD,%20Julien&H%C3%89ROGUEZ,%20Val%C3%A9rie&rft.genre=article |
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