Divanillin-Based Polyazomethines: Toward Biobased and Metal-Free π-Conjugated Polymers
GARBAY, Guillaume
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
GIRAUD, Lauriane
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
GALI, Sai Manoj
Institut des Sciences Moléculaires [ISM]
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
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Institut des Sciences Moléculaires [ISM]
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
GARBAY, Guillaume
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
GIRAUD, Lauriane
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
GALI, Sai Manoj
Institut des Sciences Moléculaires [ISM]
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
Institut des Sciences Moléculaires [ISM]
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
HADZIIOANNOU, Georges
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
GRAU, Etienne
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
GRELIER, Stéphane
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
CLOUTET, Eric
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
CRAMAIL, Henri
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
BROCHON, Cyril
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
< Reduce
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
Language
en
Article de revue
This item was published in
ACS Omega. 2020
ACS Publications
Date
2020English Abstract
Divanillin was synthesized in high yield and purity using Laccase from Trametes versicolor. It was then pol-ymerized with Benzene-1,4-diamine and 2,7-diaminocarbazole to form polyazomethines. Polymerizations were performed ...Read more >
Divanillin was synthesized in high yield and purity using Laccase from Trametes versicolor. It was then pol-ymerized with Benzene-1,4-diamine and 2,7-diaminocarbazole to form polyazomethines. Polymerizations were performed under microwave irradiation and without transition-metal based catalyst. These bio-based conjugated polyazomethines present a broad fluorescence spectrum ranging from 400 to 600 nm. Depending on the co-monomer used, polyazomethines with molar masses around 10 kg.mol-1 and with electronic gaps ranging from 2.66 to 2.85 eV were obtained. Furthermore, TD-DFT calculations were performed to corroborate experimental results.Read less <
English Keywords
Polyazomethines
Carbazole
Divanillin
Origin
Hal imported