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Metallic Nanodot Patterns with Unique Symmetries Templated from ABC Triblock Terpolymer Networks

dc.rights.licenseopen
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorAISSOU, Karim
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorMUMTAZ, Muhammad
hal.structure.identifierCentre de Recherche Paul Pascal [CRPP]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorALVAREZ-FERNANDEZ, Alberto
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorMERCAT, Jean
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorANTOINE, Ségolène
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorPÉCASTAINGS, Gilles
hal.structure.identifierCentre de Recherche Paul Pascal [CRPP]
dc.contributor.authorPONSINET, Virginie
hal.structure.identifierCertified Adaptive discRete moDels for robust simulAtions of CoMplex flOws with Moving fronts [CARDAMOM]
dc.contributor.authorDOBRZYNSKI, Cécile
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorFLEURY, Guillaume
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorHADZIIOANNOU, Georges
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2018
dc.identifier.issn1022-1336
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/19643
dc.description.abstractEnNanotemplates derived from the self-assembly of AB-type block copolymers provide an elegant route to achieve well-defined metallic dot arrays, even if the variety of pattern symmetries is restricted due to the limited number of structures offered by microphase separated diblock copolymers. A strategy that relies on the use of complex network structures accessible through the self-assembly of linear ABC-type terpolymers is presented for the formation of metallic nanodots arrays with “outside-the-box” symmetries. Patterned templates formed by the cubic Q214 and orthorhombic O70 network structures are used as excellent platforms to build well-ordered gold nanodot arrays with unique p3m1 and p2 symmetries, respectively. A simple yet efficient blending strategy is used to tune the critical dimensions of the p3m1 pattern while laterally ordered gold nanodot arrays are also demonstrated through a directed self-assembly approach. Such highly ordered gold nanodots with tunable particle dimensions and array periods, enabling the control of their plasmonic responses, are attractive probes for biological imaging.
dc.description.sponsorshipANR-10-LABX-0042-AMADEUS - null
dc.description.sponsorshipIdEx Bordeaux - ANR-10-IDEX-0003-02/10-IDEX-0003
dc.description.sponsorship“Plate-forme de l’Université de Bordeaux pour l’organique électronique imprimable : de la molécule aux dispositifs et systèmes intégrés - valorisation et commercialisation”
dc.description.sponsorshipINDUSTRIAL CHAIR HOMERIC - null
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.subject.enThin films
dc.subject.enSelf-assembly
dc.subject.enTriblock terpolymers
dc.subject.enGold nanodots
dc.subject.enNetwork structures
dc.title.enMetallic Nanodot Patterns with Unique Symmetries Templated from ABC Triblock Terpolymer Networks
dc.typeArticle de revue
dc.identifier.doi10.1002/marc.201700754
dc.subject.halChimie/Polymères
bordeaux.journalMacromolecular Rapid Communications
bordeaux.page1700754
bordeaux.volume39
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue7
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-01688010
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01688010v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Macromolecular%20Rapid%20Communications&rft.date=2018&rft.volume=39&rft.issue=7&rft.spage=1700754&rft.epage=1700754&rft.eissn=1022-1336&rft.issn=1022-1336&rft.au=AISSOU,%20Karim&MUMTAZ,%20Muhammad&ALVAREZ-FERNANDEZ,%20Alberto&MERCAT,%20Jean&ANTOINE,%20S%C3%A9gol%C3%A8ne&rft.genre=article


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