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Ring-opening polymerization of γ-lactones and copolymerization with other cyclic monomers

dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
hal.structure.identifierSouth China University of Technology [Guangzhou] [SCUT]
dc.contributor.authorSONG, Qilei
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorPASCOUAU, Chloé
hal.structure.identifierSouth China University of Technology [Guangzhou] [SCUT]
dc.contributor.authorZHAO, Junpeng
hal.structure.identifierSouth China University of Technology [Guangzhou] [SCUT]
dc.contributor.authorZHANG, Guangzhao
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorPERUCH, Frédéric
IDREF: 152900748
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorCARLOTTI, Stéphane
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2020
dc.identifier.issn0079-6700
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/19558
dc.description.abstractEnTriggered by raised environmental awareness and the rising requirements for sustainable polymers such as degradable or recyclable polymers, studies on ring-opening (co)polymerization (ROP/ROCP) of (bio-based) cyclic monomers (e.g., cyclic esters, lactides, epoxides etc.) have been booming in recent years. Renewable five-membered γ-butyrolactone (γBL) and derivatives would thus be a desirable feedstock to produce poly(γ-butyrolactone) (PγBL) and different (bio-based) functional polyesters. Their copolymerization with other cyclic monomers could also afford an alternative to tune the properties of the resulting materials. Although γBL was traditionally regarded "non-polymerizable", some progresses were made recently concerning the ROP/ROCP of γBL and derivatives. More importantly, some polyesters could be totally depolymerized back to their monomers by thermal or chemical treatment. This review is specially focused on ROP of γ-lactones and their copolymerization with other cyclic monomers by different catalytic/initiating systems, including Lewis/Brønsted acids, organic bases and alkali metal compounds, organometallic compounds, and cooperative bicomponent catalytic systems. The depolymerization process of some obtained polyesters is also discussed.
dc.language.isoen
dc.publisherElsevier
dc.subject.enγ-lactones
dc.subject.enpolyester
dc.subject.enring-opening (co)polymerization
dc.subject.ensustainable polymer
dc.title.enRing-opening polymerization of γ-lactones and copolymerization with other cyclic monomers
dc.typeArticle de revue
dc.identifier.doi10.1016/j.progpolymsci.2020.101309
dc.subject.halChimie/Polymères
bordeaux.journalProgress in Polymer Science
bordeaux.page101309
bordeaux.volume110
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-02953317
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-02953317v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Progress%20in%20Polymer%20Science&rft.date=2020&rft.volume=110&rft.spage=101309&rft.epage=101309&rft.eissn=0079-6700&rft.issn=0079-6700&rft.au=SONG,%20Qilei&PASCOUAU,%20Chlo%C3%A9&ZHAO,%20Junpeng&ZHANG,%20Guangzhao&PERUCH,%20Fr%C3%A9d%C3%A9ric&rft.genre=article


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