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hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorPRAKASAM, Mythili
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorVEBER, Philippe
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorÉTIENNE, Laetitia
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorVIRAPHONG, Oudomsack
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorLAHAYE, Michel
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorPECHEV, Stanislav
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorLEBRAUD, Eric
hal.structure.identifierNational Institute for Materials Science [NIMS]
dc.contributor.authorSHIMAMURA, Kiyoshi
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorMAGLIONE, Mario
dc.date.issued2013
dc.identifier.issn1631-0705
dc.description.abstractEnWe have grown by flux method centimeter-sized single crystals from pseudo-hexanary Li2O–Na2O–K2O–Nb2O5–Ta2O5–Sb2O3 system. Based on chemical analysis, crystals of compositions (Li0.023Na0.583K0.394)(Nb0.925Ta0.037Sb0.038)O3 and (Li0.034Na0.609K0.357)(Nb0.896Ta0.047Sb0.057)O3 were characterized by X-rays diffraction which revealed a tetragonal structure. The dielectric analysis confirmed that the ferroelectric behavior of these crystals is very sensitive to little changes in composition as previously observed on ceramics. Such high flexibility of the ferroelectric properties in crystals opens the way towards improved understanding of the relations between structure and polarization in solid solutions which may be an alternative to the lead-based materials.
dc.language.isoen
dc.publisherAcadémie des sciences (Paris)
dc.subject.enHigh temperature solution growth
dc.subject.enInorganic compound
dc.subject.enFerroelectric materials
dc.title.enGrowth and characterizations of lead-free ferroelectric KNN-based crystals
dc.typeArticle de revue
dc.identifier.doi10.1016/j.crhy.2012.10.002
dc.subject.halChimie/Matériaux
dc.subject.halChimie/Chimie inorganique
bordeaux.journalComptes Rendus. Physique
bordeaux.page133-140
bordeaux.volume14
bordeaux.issue2-3
bordeaux.peerReviewedoui
hal.identifierhal-03898249
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-03898249v1
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