Chirality determination in single crystals using XNCD and MChD
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en
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Ce document a été publié dans
Acta Crystallographica, Section A: Foundations of Crystallography, Acta Crystallographica, Section A: Foundations of Crystallography, 33rd European Crystallography Meeting, 2022-08-23, Versailles. 2022, vol. 78, n° a2, p. e718-e718
Résumé en anglais
Octahedral tris(bidentate) coordination complexes are chiral due to the propeller-like arrangement of the ligands around the metal core. The enantiomers of [M(en)3](NO3)2 (M = Mn(II), Co(II), Ni(II), Zn(II); en = ...Lire la suite >
Octahedral tris(bidentate) coordination complexes are chiral due to the propeller-like arrangement of the ligands around the metal core. The enantiomers of [M(en)3](NO3)2 (M = Mn(II), Co(II), Ni(II), Zn(II); en = ethylenediamine) spontaneously resolve to form a mixture of conglomerate crystals in the space group P6322 at room temperature [1]...< Réduire
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