Chirality determination in single crystals using XNCD and MChD
Language
en
Communication dans un congrès
This item was published in
Acta Crystallographica, Section A: Foundations of Crystallography, Acta Crystallographica, Section A: Foundations of Crystallography, 33rd European Crystallography Meeting, 2022-08-23, Versailles. 2022, vol. 78, n° a2, p. e718-e718
English Abstract
Octahedral tris(bidentate) coordination complexes are chiral due to the propeller-like arrangement of the ligands around the metal core. The enantiomers of [M(en)3](NO3)2 (M = Mn(II), Co(II), Ni(II), Zn(II); en = ...Read more >
Octahedral tris(bidentate) coordination complexes are chiral due to the propeller-like arrangement of the ligands around the metal core. The enantiomers of [M(en)3](NO3)2 (M = Mn(II), Co(II), Ni(II), Zn(II); en = ethylenediamine) spontaneously resolve to form a mixture of conglomerate crystals in the space group P6322 at room temperature [1]...Read less <
Origin
Hal imported