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Dynamic Covalent Bond: Modes of Activation of the C—ON Bond in Alkoxyamines

dc.rights.licenseopenen_US
dc.contributor.authorAUDRAN, Gérard
dc.contributor.authorBAGRYANSKAYA, Elena G.
dc.contributor.authorBIKANGA, Raphaël
dc.contributor.authorCOOTE, Michelle L.
dc.contributor.authorGUSELNIKOVA, Olga
dc.contributor.authorHAMMILL, Chelsey L.
dc.contributor.authorMARQUE, Sylvain R. A.
hal.structure.identifierCentre de résonance magnétique des systèmes biologiques [CRMSB]
dc.contributor.authorMELLET, Philippe
dc.contributor.authorPOSTNIKOV, Pavel S.
dc.date.accessioned2023-11-16T08:00:17Z
dc.date.available2023-11-16T08:00:17Z
dc.date.issued2023-07-01
dc.identifier.issn0079-6700en_US
dc.identifier.urioai:crossref.org:10.1016/j.progpolymsci.2023.101726
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/184797
dc.description.abstractEnThe materials of future depend a lot on properties that are due to “non stable” molecules. Hence, Dynamic Covalent Bonds (DCB) are covalent bonds that are labile under specific stimuli and are integral to the design of next generation materials. Alkoxyamines R1R2NO—R3 exhibit a unique C—O DCB that is nonsymmetric between the adjacent O- and C-atoms. This bond can be cleaved homolytically, heterolytically and mesolytically in response to a wide variety of physical, chemical and biological stimuli, and the kinetics and thermodynamics of cleavage can be tuned on-demand by varying the structure of R1, R2 and R3. Alkoxyamines are easily incorporated into polymers via nitroxide mediated polymerisation (NMP) however, their dynamic covalent properties are yet to be fully exploited in materials sciences. This is in part because reports on C—ON activation are scattered through the broader synthetic, physical and biological chemistry literature, and a comprehensive review of them has been lacking. Herein, 20 leading C—ON activation processes using UV-light, surface plasmon resonance, magnetothermy, electrochemistry, chemical oxidation, protonation, non-covalent bonding, sonication, enzymatic activation among others, are presented and discussed, along with primary examples of their application.
dc.description.sponsorshipNouveaux amorceurs pour la polymérisation radicalaire - ANR-14-CE06-0023en_US
dc.description.sponsorshipAlkoxyamines comme substituts aux amorceurs de types pe´roxydiques ou azoi¨ques utilise´s en polyme´risation radicalaireen_US
dc.description.sponsorshipUtilisation d'alkoxyamines intélligents comme inhibiteurs radicalaires pour controller la polymérisation - ANR-21-CE06-0044en_US
dc.description.sponsorshipNanoparticules conjuguées à des alkoxyamines activées par des stimuli externes comme agents antibactériens pour les plantes - ANR-22-CE09-0026en_US
dc.language.isoENen_US
dc.sourcecrossref
dc.title.enDynamic Covalent Bond: Modes of Activation of the C—ON Bond in Alkoxyamines
dc.typeArticle de revueen_US
dc.identifier.doi10.1016/j.progpolymsci.2023.101726en_US
dc.subject.halSciences du Vivant [q-bio]en_US
dc.subject.halSciences de l'ingénieur [physics]en_US
bordeaux.journalProgress in Polymer Scienceen_US
bordeaux.page101726en_US
bordeaux.hal.laboratoriesCentre de Résonance Magnétique des Systèmes Biologiques (CRMSB) - UMR 5536en_US
bordeaux.institutionUniversité de Bordeauxen_US
bordeaux.institutionCNRSen_US
bordeaux.peerReviewedouien_US
bordeaux.inpressnonen_US
bordeaux.import.sourcedissemin
hal.identifierhal-04288455
hal.version1
hal.date.transferred2023-11-16T08:00:20Z
hal.popularnonen_US
hal.audienceInternationaleen_US
hal.exporttrue
workflow.import.sourcedissemin
dc.rights.ccPas de Licence CCen_US
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