We theoretically and experimentally investigate light diffusion in disordered meso-macroporous materials with a cylindrical shape. High Internal Phase Emulsion (HIPE)-based silica foam samples, exhibiting a polydisperse pore-size distribution centered around 19 μm to resemble certain biological tissues, are realized. To quantify the effect of a finite lateral size on measurable quantities, an analytical model for diffusion in finite cylinders is developed and validated by Monte Carlo random walk simulations. Steady-state and time-resolved transmission experiments are performed and the transport parameters (transport mean free path and material absorption length) are successfully retrieved from fits of the experimental curves with the proposed model. This study reveals that scattering losses on the lateral sides of the samples are responsible for a lowering of the transmission signal and a shortening of the photon lifetime, similar in experimental observables to the effect of material absorption. The recognition of this geometrical effect is essential since its wrong attribution to material absorption could be detrimental in various applications, such as biological tissue diagnosis or conversion efficiency in dye-sensitized solar cells.< Leer menos