Systematic XPS studies of metal oxides, hydroxides and peroxides
hal.structure.identifier | Institut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux [IPREM] | |
dc.contributor.author | DUPIN, Jean-Charles | |
hal.structure.identifier | Institut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux [IPREM] | |
dc.contributor.author | GONBEAU, Danielle | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | VINATIER, Philippe | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | LEVASSEUR, Alain | |
dc.date.issued | 2000 | |
dc.identifier.issn | 1463-9076 | |
dc.description.abstractEn | The results of a systematic XPS study, under high controlled conditions, of different basic oxides of transition metals, alkali and alkaline-earth metals are presented; the XPS data of some hydroxides and peroxides are also reported. Variations of the O 1s binding energies are analysed and one point of interest is the large binding energy scale obtained for O 1s peaks all associated with a '2-' formal charge. Through extended Huckel theory-tight binding (EHT-TB) calculations, attempts are made to rationalize the observed variations. The results illustrate the significant differences between real charges on oxygen atoms in transition metal and alkaline-earth oxides. | |
dc.language.iso | en | |
dc.publisher | Royal Society of Chemistry | |
dc.title.en | Systematic XPS studies of metal oxides, hydroxides and peroxides | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1039/a908800h | |
dc.subject.hal | Chimie/Matériaux | |
dc.subject.hal | Chimie/Chimie inorganique | |
bordeaux.journal | Physical Chemistry Chemical Physics | |
bordeaux.page | 1319-1324 | |
bordeaux.volume | 2 | |
bordeaux.issue | 6 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-01636425 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-01636425v1 | |
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