Crystal structure of cyclohexylammonium hydrogen maleate salt hemi-hydrated
Language
en
Article de revue
This item was published in
Mediterranean Journal of Chemistry. 2023, vol. 13, n° 1, p. 1-7
Mediterranean Journal of Chemistry
English Abstract
The compound CyNH3[HOOC(CH)2COO]•H2O has been obtained using one pot-synthesis process by mixing, in methanol, HOOC(CH)2COOH, CyNH2 and SnPh3Cl in a 1:1:1 molar ratio. X-ray diffraction analysis of the compound reveals ...Read more >
The compound CyNH3[HOOC(CH)2COO]•H2O has been obtained using one pot-synthesis process by mixing, in methanol, HOOC(CH)2COOH, CyNH2 and SnPh3Cl in a 1:1:1 molar ratio. X-ray diffraction analysis of the compound reveals that in the crystal structure, hydrogen maleate [HOOC(CH)2COO]-in cis configuration interacts with [CyNH3] + cations and water molecules to generate an R6 6 (22) ring. The interconnections of the rings via simple (N-H••O and O-H••O) and bifurcated (N-H•••(O, O)) hydrogen bonds give rise to a 2D supramolecular structure.Read less <
English Keywords
Crystal structure
maleate anion
an infinite 2D network graph set notation
N–H···O hydrogen bond
Origin
Hal imported