Lab-scale investigation of the ability of Polar Organic Chemical Integrative Sampler to catch short pesticide contamination peaks
Idioma
EN
Article de revue
Este ítem está publicado en
Environmental Science and Pollution Research. 2022-01, vol. 29, p. 40-50
Resumen en inglés
In this lab-scale study, the POCIS capacity to integrate short contamination peaks of variable intensity and duration was evaluated. POCIS were immersed for 14 days in tanks filled with tap water and spiked at different ...Leer más >
In this lab-scale study, the POCIS capacity to integrate short contamination peaks of variable intensity and duration was evaluated. POCIS were immersed for 14 days in tanks filled with tap water and spiked at different concentrations with 12 pesticides of various polarities (log Kow = 1.1–4.7) and classes (herbicides, fungicides, and insecticides). Concentrations were kept relatively constant at 1 μg L−1 and 5 μg L−1, respectively, in two “background” exposure tanks. Three contamination peaks of increasing intensity and decreasing duration were simulated (10 μg L−1 for 24 h, 40 μg L−1 for 6 h, and 60 μg L−1 for 1 h). This lab-scale study demonstrated that ten moderately polar compounds (2 < log Kow < 4) showed a linear uptake, as observed in previous studies, while a non-linear model fits the data of the two most polar pesticides (log Kow < 2). Depending on chemical polarity, some compounds exhibited a “burst effect” or “lag effect” during the first 3 days of exposure. After 14 days of exposure, contamination peaks appeared integrated for seven compounds, showing the ability of POCIS to catch very short pollution events and to provide acceptable time-weighted average concentration estimates under laboratory-controlled conditions.< Leer menos
Palabras clave en inglés
POCIS
Pesticides
Fleeting events
Model selection
Laboratory-controlled conditions
Centros de investigación