Afficher la notice abrégée

Biosourced Polymeric Emulsifiers for Miniemulsion Copolymerization of Myrcene and Styrene: towards biobased Waterborne Latex as Pickering Emulsion Stabilizer

dc.rights.licenseopenen_US
dc.contributor.authorSAVE, Maud
hal.structure.identifierCentre de Recherche Paul Pascal [CRPP]
dc.contributor.authorLE HELLAYE, Maude
hal.structure.identifierCentre de Recherche Paul Pascal [CRPP]
dc.contributor.authorDE VILLEDON, Valentine
dc.contributor.authorADOUMAZ, Ismail
dc.contributor.authorPILLET, Marion
dc.contributor.authorATANASE, Léonard
dc.contributor.authorLAHCINI, Mohammed
dc.contributor.authorDENIAU-LEJEUNE, Elise
dc.contributor.authorKHOUKH, Abdel
dc.contributor.authorPELLERIN, Virginie
hal.structure.identifierCentre de Recherche Paul Pascal [CRPP]
dc.contributor.authorLY, Isabelle
dc.contributor.authorDULONG, Virginie
hal.structure.identifierCentre de Recherche Paul Pascal [CRPP]
dc.contributor.authorSCHMITT, Véronique
dc.date.accessioned2022-10-29T10:15:20Z
dc.date.available2022-10-29T10:15:20Z
dc.date.issued2022-05-31
dc.identifier.issn1525-7797en_US
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/170157
dc.description.abstractEnBiobased waterborne latexes were synthesized by miniemulsion radical copolymerization of biosourced -myrcene (My) terpenic monomer and styrene (S). Biobased amphiphilic copolymers were designed to act as stabilizers of the initial monomer droplets and the polymer colloids dispersed in the water phase. Two types of hydrophilic polymer backbones were hydrophobically modified by terpene molecules to synthesize two series of amphiphilic copolymers with various degrees of substitution. The first series consists of poly(acrylic acid) modified with tetrahydrogeraniol moieties (PAA-g-THG) and the second series is based on the polysaccharide carboxymethylpullulan amino-functionalized with dihydromyrcenol moieties (CMP-g-(NH-DHM)). The produced waterborne latexes with diameters between 160 and 300 nm and were composed of polymers with varying glass transition temperatures (Tg, PMy =-60°C, Tg, P(My-coS) =-14°C, Tg, PS = 105 °C) depending on the molar fraction of biobased -myrcene (fMy,0 = 0, 0.43 or 1). The latexes successfully stabilized dodecane-inwater and water-in-dodecane emulsions for months at all compositions. The waterborne latexes composed of low Tg poly(-myrcene) caused interesting different behavior during drying of the emulsions compared to polystyrene latexes.
dc.language.isoENen_US
dc.title.enBiosourced Polymeric Emulsifiers for Miniemulsion Copolymerization of Myrcene and Styrene: towards biobased Waterborne Latex as Pickering Emulsion Stabilizer
dc.typeArticle de revueen_US
dc.identifier.doi10.1021/acs.biomac.2c00257en_US
dc.subject.halChimieen_US
dc.subject.halChimie/Polymèresen_US
bordeaux.journalBiomacromoleculesen_US
bordeaux.hal.laboratoriesCentre de Recherche Paul Pascal (CRPP) - UMR 5031en_US
bordeaux.institutionUniversité de Bordeauxen_US
bordeaux.institutionCNRSen_US
bordeaux.peerReviewedouien_US
bordeaux.inpressnonen_US
bordeaux.import.sourcehal
hal.identifierhal-03690323
hal.version1
hal.exportfalse
workflow.import.sourcehal
dc.rights.ccPas de Licence CCen_US
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Biomacromolecules&rft.date=2022-05-31&rft.eissn=1525-7797&rft.issn=1525-7797&rft.au=SAVE,%20Maud&LE%20HELLAYE,%20Maude&DE%20VILLEDON,%20Valentine&ADOUMAZ,%20Ismail&PILLET,%20Marion&rft.genre=article


Fichier(s) constituant ce document

FichiersTailleFormatVue

Il n'y a pas de fichiers associés à ce document.

Ce document figure dans la(les) collection(s) suivante(s)

Afficher la notice abrégée