DOULIEZ, Jean-Paul; MARTIN, Nicolas; GAILLARD, Cédric; BENEYTON, Thomas; BARET, Jean-Christophe; MANN, Stephen; BEVEN, Laure

doi:10.1002/anie.201707139

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DOULIEZ, Jean-Paul
Biologie du fruit et pathologie [BFP]

MARTIN, Nicolas
University of Bristol [Bristol]

GAILLARD, Cédric
Unité de recherche sur les Biopolymères, Interactions Assemblages [BIA]

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Angewandte Chemie International Edition. 2017-10-23, vol. 56, n° 44, p. 13689 - 13693

Wiley-VCH Verlag

Resumen en inglés

We report on the formation of surfactant-based complex catanionic coacervate droplets in mixtures of decanoic acid and cetylpyridinium chloride or cetyltrimethylammonium bromide. We show that coacervation occurs over a broad range of composition, pH, and ionic strength. The catanionic coacervates consist of elongated micelles, sequester a wide range of solutes including water-soluble organic dyes, polysaccharides, proteins, enzymes, and DNA, and can be structurally stabilized by sodium alginate or gelatin-based hydrogelation. These results suggest that catanionic coacervates could be exploited as a novel surfactant-based membrane- free protocell model.< Leer menos

Palabras clave en inglés

Catanionics · Coacervates · Microreactors · Protein crowding · Sequestration

DOI

http://dx.doi.org/10.1002/anie.201707139

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