Orientational order in the stable buckminster fullerene solvate C60.2CBr2H2
| hal.structure.identifier | Departament de Fisica i Enginyeria Nuclear [UPC, Barcelone] [ETSEIB] | |
| dc.contributor.author | YE, J. | |
| hal.structure.identifier | Departament de Fisica i Enginyeria Nuclear [UPC, Barcelone] [ETSEIB] | |
| dc.contributor.author | BARRIO, M. | |
| hal.structure.identifier | Laboratoire Ondes et Matière d'Aquitaine [LOMA] | |
| dc.contributor.author | NEGRIER, Ph. | |
| hal.structure.identifier | Institut Laue-Langevin [ILL] | |
| dc.contributor.author | QURESHI, N. | |
| hal.structure.identifier | Faculté des sciences pharmaceutiques et biologiques | |
| dc.contributor.author | RIETVELD, I. B. | |
| hal.structure.identifier | Departament de Fisica i Enginyeria Nuclear [UPC, Barcelone] [ETSEIB] | |
| dc.contributor.author | CÉOLIN, R. | |
| hal.structure.identifier | Departament de Fisica i Enginyeria Nuclear [UPC, Barcelone] [ETSEIB] | |
| dc.contributor.author | TAMARIT, Josep Ll | |
| dc.date.created | 2016-09-15 | |
| dc.date.issued | 2017-04 | |
| dc.identifier.issn | 1951-6355 | |
| dc.description.abstractEn | Crystals of the solvate C 60 ·2CBr 2 H 2 (monoclinic C2/m), which is stable in air, were grown by slow evaporation of solutions of C 60 in CBr 2 H 2 at room temperature. The high enthalpy change for the complete desolvation process, 54.9 kJ mol-1 of solvent, as well as the relatively large negative excess volume of-49.6 Å 3 indicate the presence of strong intermolecular interactions between C 60 and CBr 2 H 2. The strong intermolecular interactions are consistent with an overall orientational order for the C 60 and the CBr 2 H 2 molecules in the solvate as found by the Rietveld refinement of its crystal structure. | |
| dc.language.iso | en | |
| dc.publisher | EDP Sciences | |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-sa/ | |
| dc.title.en | Orientational order in the stable buckminster fullerene solvate C60.2CBr2H2 | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1140/epjst/e2016-60272-x | |
| dc.subject.hal | Chimie/Cristallographie | |
| bordeaux.journal | The European Physical Journal. Special Topics | |
| bordeaux.page | 857-867 | |
| bordeaux.volume | 226 | |
| bordeaux.issue | 5 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01542751 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01542751v1 | |
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