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Measurement and Analysis of the Naphthalene - Octafluoronaphthalene Phase Diagram: Complex Formation in Solid and Liquid

hal.structure.identifierCentre de physique moléculaire optique et hertzienne [CPMOH]
dc.contributor.authorMICHAUD, F.
hal.structure.identifierCentre de physique moléculaire optique et hertzienne [CPMOH]
dc.contributor.authorNÉGRIER, Philippe
hal.structure.identifierCentre de physique moléculaire optique et hertzienne [CPMOH]
dc.contributor.authorMIKAILITCHENKO, D.
hal.structure.identifierCentre de physique moléculaire optique et hertzienne [CPMOH]
dc.contributor.authorMARBEUF, A.
hal.structure.identifierCentre de physique moléculaire optique et hertzienne [CPMOH]
dc.contributor.authorHAGET, Y.
hal.structure.identifierDepartament de crystalografia
dc.contributor.authorCUEVAS-DIARTE, M.
hal.structure.identifierDebye Institute, Department of Interfaces and Thermodynamics
dc.contributor.authorOONK, H. A. J.
dc.date.created1998-03-24
dc.date.issued1999
dc.identifier.issn1542-1406
dc.description.abstractEnNaphthalene–octafluoronaphthalene room pressure solid–liquid phase diagram has been assessed by means of differential scanning calorimetry and powder X-ray diffraction analyses. Thermodynamic properties are analysed through the associated liquid model. The solid states consists of six crystalline phases with well defined composition: one for naphthalene, two for octafluoronaphthalene and three for an equimolecular intermolecular compound. This complex melts congruently at (406.3±0.3) K, i.e., about fifty degrees higher than its components and the resulting liquid is moderately associated. The solid–solid phase transitions of this complex are strongly energetic. The corresponding overall change of entropy stands for two third times the entropy of fusion. The consecutive increasing of crystalline symmetry and positional disorder is clearly visible on diffraction patterns.
dc.language.isoen
dc.publisherTaylor & Francis
dc.subject.enOctafluoronaphthalene
dc.subject.ennaphthalene
dc.subject.enmolecular complexes
dc.subject.enassociated liquid
dc.title.enMeasurement and Analysis of the Naphthalene - Octafluoronaphthalene Phase Diagram: Complex Formation in Solid and Liquid
dc.typeArticle de revue
dc.identifier.doi10.1080/10587259908025429
dc.subject.halPhysique [physics]
dc.subject.halChimie/Cristallographie
bordeaux.journalMolecular Crystals and Liquid Crystals
bordeaux.page409-424
bordeaux.volume326
bordeaux.issue1
bordeaux.peerReviewedoui
hal.identifierhal-01550369
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01550369v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Molecular%20Crystals%20and%20Liquid%20Crystals&rft.date=1999&rft.volume=326&rft.issue=1&rft.spage=409-424&rft.epage=409-424&rft.eissn=1542-1406&rft.issn=1542-1406&rft.au=MICHAUD,%20F.&N%C3%89GRIER,%20Philippe&MIKAILITCHENKO,%20D.&MARBEUF,%20A.&HAGET,%20Y.&rft.genre=article


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