Equilibration between three different excited states in a bichromophoric copper(I) polypyridine complex
Language
en
Article de revue
This item was published in
Journal of the American Chemical Society. 2007-07-18, vol. 129, n° 28, p. 8688-8689
American Chemical Society
English Abstract
Fast reversible energy transfer and intersystem crossing conspire to permit excited-state equilibration between three excited states in a copper(I) phenanthroline complex. Introduction of multiple quasi-isoenergetic excited ...Read more >
Fast reversible energy transfer and intersystem crossing conspire to permit excited-state equilibration between three excited states in a copper(I) phenanthroline complex. Introduction of multiple quasi-isoenergetic excited states in a planned fashion represents a new strategy to prolong luminescence lifetimes of copper phenanthroline complexes (e.g., 1.2 μs compared with 70 ns for the parent complex).Read less <
Origin
Hal imported