NÉGRIER, Philippe; TAMARIT, Josep Ll; BARRIO, María; PARDO, Luis C.; MONDIEIG, Denise

doi:10.1016/j.chemphys.2007.06.008

Metadatos

Mostrar el registro completo del ítem

Licencia de uso del documento

http://creativecommons.org/licenses/by-sa/

NÉGRIER, Philippe
Centre de physique moléculaire optique et hertzienne [CPMOH]

TAMARIT, Josep Ll
Departament de Fisica i Enginyeria Nuclear [UPC, Barcelone] [ETSEIB]

BARRIO, María
Departament de Fisica i Enginyeria Nuclear [UPC, Barcelone] [ETSEIB]

Idioma

Article de revue

Este ítem está publicado en

Chemical Physics. 2007, vol. 336, n° 2-3, p. 150-156

Elsevier

Resumen en inglés

On the basis of the isostructural relationship between the low-temperature monoclinic (C2/c, Z = 32) phases of the halogenomethane CBr4-nCln (n = 0,...,4), a set of mixed crystals has been analysed by means of high-resolution X-ray powder diffraction. It is shown that the monoclinic structure of pure and mixed crystals does not depend of the particularities of the dipolar (or dipole induced) interactions of the pure compound, neither on the composition of the mixed crystal, but on the relative content of the halogen atoms which controls the size of the molecule or the average molecule for the case of mixed crystals.< Leer menos

Palabras clave en inglés

Mixed crystals

Disorder

Vegard law

Halogenomethanes

Metadatos

Licencia de uso del documento

Monoclinic mixed crystals of halogenomethanes CBr4-nCln (n=0,...,4)

Idioma

Este ítem está publicado en

Resumen en inglés

Palabras clave en inglés

DOI

Orígen

Centros de investigación