Second harmonic and terahertz generation in a Prussian-blue-analog.
| hal.structure.identifier | Laboratoire Ondes et Matière d'Aquitaine [LOMA] | |
| dc.contributor.author | OULD-HAMOUDA, Amine | |
| hal.structure.identifier | Laboratoire Ondes et Matière d'Aquitaine [LOMA] | |
| dc.contributor.author | IAZZOLINO, Antonio | |
| hal.structure.identifier | Department of Chemistry [Tokyo] | |
| hal.structure.identifier | Division of Materials Science [Tsukuba] | |
| dc.contributor.author | TOKORO, Hiroko | |
| hal.structure.identifier | Department of Chemistry [Tokyo] | |
| dc.contributor.author | OHKOSHI, Shin-Ichi | |
| hal.structure.identifier | Laboratoire Ondes et Matière d'Aquitaine [LOMA] | |
| dc.contributor.author | FREYSZ, Eric | |
| dc.date.created | 2017-08-14 | |
| dc.date.issued | 2018-01-31 | |
| dc.identifier.issn | 1434-1948 | |
| dc.description.abstractEn | Second-harmonic and terahertz generation are performed in Rb0.94Mn[Fe(CN)6]0.98.0.3H2O Prussian-blue-analog. Second-harmonic generation experiments are carried out in between 1100 and 1700 nm and within the hysteresis loop of this compound. In the low and high temperature phases, our measurements indicate that the effective second-order nonlinear component χ (2) of this material is small compared to -Quartz. However at high temperature phase and close to 1100 nm, its χ (2) is enhanced by more than one order of magnitude. Terahertz generation performed indicates that in this frequency range, the effective χ (2) of this compound is high and comparable to ZnTe. Finally we demonstrate that, within the thermal hysteresis loop of this Prussian-blue-analog, one can modulate the χ (2) by photo-switching it from the low temperature to the high temperature phase. | |
| dc.description.sponsorship | Vers une génération de Gel-Coats Intelligents : thermo- et/ou photosensibles | |
| dc.language.iso | en | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-sa/ | |
| dc.subject.en | Prussian-blue-analog | |
| dc.subject.en | THz generation | |
| dc.subject.en | Second harmonic generation | |
| dc.subject.en | Photo-switching | |
| dc.subject.en | Coordination Chemistry | |
| dc.title.en | Second harmonic and terahertz generation in a Prussian-blue-analog. | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1002/ejic.201700980 | |
| dc.subject.hal | Chimie/Chimie de coordination | |
| dc.subject.hal | Chimie/Chimie inorganique | |
| dc.subject.hal | Physique [physics]/Matière Condensée [cond-mat]/Science des matériaux [cond-mat.mtrl-sci] | |
| bordeaux.journal | European Journal of Inorganic Chemistry | |
| bordeaux.page | 378-384 | |
| bordeaux.volume | 2018 | |
| bordeaux.issue | 3-4 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01630454 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01630454v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=European%20Journal%20of%20Inorganic%20Chemistry&rft.date=2018-01-31&rft.volume=2018&rft.issue=3-4&rft.spage=378-384&rft.epage=378-384&rft.eissn=1434-1948&rft.issn=1434-1948&rft.au=OULD-HAMOUDA,%20Amine&IAZZOLINO,%20Antonio&TOKORO,%20Hiroko&OHKOSHI,%20Shin-Ichi&FREYSZ,%20Eric&rft.genre=article |
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