Polymorphism of 2-Adamantanone
| hal.structure.identifier | Laboratoire Ondes et Matière d'Aquitaine [LOMA] | |
| dc.contributor.author | NÉGRIER, Philippe | |
| hal.structure.identifier | Departament de Fisica i Enginyeria Nuclear [UPC, Barcelone] [ETSEIB] | |
| dc.contributor.author | BARRIO, M. | |
| hal.structure.identifier | Departament de Fisica i Enginyeria Nuclear [UPC, Barcelone] [ETSEIB] | |
| dc.contributor.author | ROMANINI, M. | |
| hal.structure.identifier | Departament de Fisica i Enginyeria Nuclear [UPC, Barcelone] [ETSEIB] | |
| dc.contributor.author | TAMARIT, Josep Lluis | |
| hal.structure.identifier | Laboratoire Ondes et Matière d'Aquitaine [LOMA] | |
| dc.contributor.author | MONDIEIG, Denise | |
| hal.structure.identifier | B. Verkin Institute for Low Temperature Physics and Engineering [ILTPE] | |
| dc.contributor.author | KRIVCHIKOV, A. I. | |
| hal.structure.identifier | Institute of Low Temperature and Structure Research [Polish Academy of Sciences] | |
| dc.contributor.author | KEPINSKI, L. | |
| hal.structure.identifier | Institute of Low Temperature and Structure Research [Polish Academy of Sciences] | |
| dc.contributor.author | JEZOWSKI, A. | |
| hal.structure.identifier | Institute of Low Temperature and Structure Research [Polish Academy of Sciences] | |
| dc.contributor.author | SZEWCZYK, D. | |
| dc.date.created | 2014-03-03 | |
| dc.date.issued | 2014 | |
| dc.identifier.issn | 1528-7483 | |
| dc.description.abstractEn | The polymorphism of 2-adamantanone (C10H14O) has been investigated by means of X-ray diffraction and high-pressure thermal analysis. The intricate behavior of the low-temperature crystalline phases has been disentangled. The stable phase has been found to be orthorhombic (Cmc21, Z = 4), fully ordered, with lattice parameters a = 6.8884(18) Å, b = 10.830(3) Å, c = 10.658(3) Å, and V/Z = 198.8(1) Å3. The metastable phase was determined to be monoclinic (P21/c, Z = 4) with lattice parameters a = 6.5920(17) Å, b = 11.118(3) Å, c = 12.589(3) Å, beta= 118.869(11) °, and V/Z = 202.0(1) Å3. The pressure-temperature phase diagram irrefutably shows the stability relation between both phases and, accordingly, the long-time unknown polymorphic behavior is now revealed and gives coherent physical explanation of the literature published so far. | |
| dc.language.iso | en | |
| dc.publisher | American Chemical Society | |
| dc.rights.uri | http://creativecommons.org/licenses/by-sa/ | |
| dc.title.en | Polymorphism of 2-Adamantanone | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1021/cg500313m | |
| dc.subject.hal | Chimie/Cristallographie | |
| bordeaux.journal | Crystal Growth & Design | |
| bordeaux.page | 2626-2632 | |
| bordeaux.volume | 14 | |
| bordeaux.issue | 5 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00999243 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00999243v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Crystal%20Growth%20&%20Design&rft.date=2014&rft.volume=14&rft.issue=5&rft.spage=2626-2632&rft.epage=2626-2632&rft.eissn=1528-7483&rft.issn=1528-7483&rft.au=N%C3%89GRIER,%20Philippe&BARRIO,%20M.&ROMANINI,%20M.&TAMARIT,%20Josep%20Lluis&MONDIEIG,%20Denise&rft.genre=article |
Fichier(s) constituant ce document
| Fichiers | Taille | Format | Vue |
|---|---|---|---|
|
Il n'y a pas de fichiers associés à ce document. |
|||