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New Synthetic Routes towards Soluble and Dissymmetric Triphenodioxazine Dyes Designed for Dye-Sensitized Solar Cells

hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorNICOLAS, Yohann
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorALLAMA, Fouzia
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorLEPELTIER, Marc
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorMASSIN, Julien
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorCASTET, Frédéric
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorDUCASSE, Laurent
hal.structure.identifierLaboratoire de l'intégration, du matériau au système [IMS]
dc.contributor.authorHIRSCH, Lionel
hal.structure.identifierLaboratoire Ondes et Matière d'Aquitaine [LOMA]
dc.contributor.authorBOUBEGTITEN, Zahia
hal.structure.identifierLaboratoire Ondes et Matière d'Aquitaine [LOMA]
dc.contributor.authorJONUSAUSKAS, Gediminas
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorOLIVIER, Céline
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorTOUPANCE, Thierry
dc.date.created2013-09-26
dc.date.issued2014
dc.identifier.issn0947-6539
dc.description.abstractEnNew π-conjugated structures are constantly the subject of research in dyes and pigments industry and electronic organic field. In this context, the triphenodioxazine (TPDO) core has often been used as efficient photostable pigments and once integrated in air stable n-type organic field-effect transistor (OFET). However, little attention has been paid to the TPDO core as soluble materials for optoelectronic devices, possibly due to the harsh synthetic conditions and the insolubility of many compounds. To benefit from the photostability of TPDO in dye-sensitized solar cells (DSCs), an original synthetic pathway has been established to provide soluble and dissymmetric molecules applied to a suitable design for the sensitizers of DSC. The study has been pursued by the theoretical modeling of opto-electronic properties, the optical and electronic characterizations of dyes and elaboration of efficient devices. The discovery of new synthetic pathways opens the way to innovative designs of TPDO for materials used in organic electronics.
dc.description.sponsorshipMatériaux hybrides fonctionnels pour la conversion de l'énergie solaire en électricité - ANR-10-BLAN-0938
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.rights.urihttp://creativecommons.org/licenses/by-nc/
dc.title.enNew Synthetic Routes towards Soluble and Dissymmetric Triphenodioxazine Dyes Designed for Dye-Sensitized Solar Cells
dc.typeArticle de revue
dc.identifier.doi10.1002/chem.201303775
dc.subject.halChimie/Chimie organique
dc.subject.halPhysique [physics]/Physique [physics]/Chimie-Physique [physics.chem-ph]
bordeaux.journalChemistry - A European Journal
bordeaux.page3678-3688
bordeaux.volume20
bordeaux.issue13
bordeaux.peerReviewedoui
hal.identifierhal-00968910
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00968910v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Chemistry%20-%20A%20European%20Journal&rft.date=2014&rft.volume=20&rft.issue=13&rft.spage=3678-3688&rft.epage=3678-3688&rft.eissn=0947-6539&rft.issn=0947-6539&rft.au=NICOLAS,%20Yohann&ALLAMA,%20Fouzia&LEPELTIER,%20Marc&MASSIN,%20Julien&CASTET,%20Fr%C3%A9d%C3%A9ric&rft.genre=article


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