Ordering of anisotropic polarizable polymer chains on the full many-body level
DEAN, David
Physique Statistique des Systèmes Complexes (LPT) [PhyStat]
Laboratoire Ondes et Matière d'Aquitaine [LOMA]
Physique Statistique des Systèmes Complexes (LPT) [PhyStat]
Laboratoire Ondes et Matière d'Aquitaine [LOMA]
DEAN, David
Physique Statistique des Systèmes Complexes (LPT) [PhyStat]
Laboratoire Ondes et Matière d'Aquitaine [LOMA]
< Leer menos
Physique Statistique des Systèmes Complexes (LPT) [PhyStat]
Laboratoire Ondes et Matière d'Aquitaine [LOMA]
Idioma
en
Article de revue
Este ítem está publicado en
Journal of Chemical Physics. 2012, vol. 136, n° 15, p. 154905
American Institute of Physics
Resumen en inglés
We study the effect of dielectric anisotropy of polymers on their equilibrium ordering within mean-field theory but with a formalism that takes into account the full n-body nature of van der Waals forces. Dielectric ...Leer más >
We study the effect of dielectric anisotropy of polymers on their equilibrium ordering within mean-field theory but with a formalism that takes into account the full n-body nature of van der Waals forces. Dielectric anisotropy within polymers is to be expected as the electronic properties of the polymer will typically be different along the polymer than across its cross section. It is therefore physically intuitive that larger charge fluctuations can be induced along the chain than perpendicular to it. We show that this dielectric anisotropy leads to n-body interactions which can induce an isotropic--nematic transition. The two body and three body components of the full van der Waals interaction are extracted and it is shown how the two body term behaves like the phenomenological self-aligning-pairwise nematic interaction. At the three body interaction level we see that the nematic phase that is energetically favorable is discotic, however on the full n-body interaction level we find that the normal axial nematic phase is always the stable ordered phase. The n-body nature of our approach also shows that the key parameter driving the nematic-isotropic transition is the bare persistence length of the polymer chain.< Leer menos
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