Unraveling the mechanism of NO ligand photoisomerism by time-resolved infrared spectroscopy
| hal.structure.identifier | Laboratoire Ondes et Matière d'Aquitaine [LOMA] | |
| dc.contributor.author | GALLÉ, Geoffrey | |
| hal.structure.identifier | Physikalisches Institut [Köln] | |
| dc.contributor.author | NICOUL, Matthieu | |
| hal.structure.identifier | Institut für Strukturphysik | |
| dc.contributor.author | WOIKE, Theo | |
| hal.structure.identifier | Cristallographie, Résonance Magnétique et Modélisations [CRM2] | |
| dc.contributor.author | SCHANIEL, Dominik | |
| hal.structure.identifier | Laboratoire Ondes et Matière d'Aquitaine [LOMA] | |
| dc.contributor.author | FREYSZ, Eric | |
| dc.date.created | 2012-05-07 | |
| dc.date.issued | 2012 | |
| dc.identifier.issn | 0009-2614 | |
| dc.description.abstractEn | UV-Vis- and infrared femtosecond spectroscopy makes it possible to reveal all different steps of photochemical reactions after the electronic excitation. The electronic relaxations are observed in the UV-Vis spectral range whereas the nuclear motions are monitored in the infrared spectral range. We used femtosecond time-resolved infrared spectroscopy to demonstrate the photoisomerization of the NO ligand photoinduced by a visible femtosecond pulse in a Na2[Fe(CN)5NO]*2H2O single crystal occurs in about 350 fs. The analysis of data makes it possible to unravel the mechanism leading to the photoisomerization of the NO ligand. | |
| dc.description.sponsorship | / - ANR-09-BLAN-0212 | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-sa/ | |
| dc.title.en | Unraveling the mechanism of NO ligand photoisomerism by time-resolved infrared spectroscopy | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/J.CPLETT.2012.09.071 | |
| dc.subject.hal | Chimie/Chimie théorique et/ou physique | |
| dc.subject.hal | Physique [physics]/Physique [physics]/Optique [physics.optics] | |
| bordeaux.journal | Chemical Physics Letters | |
| bordeaux.page | 64-68 | |
| bordeaux.volume | 552 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00772561 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00772561v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Chemical%20Physics%20Letters&rft.date=2012&rft.volume=552&rft.spage=64-68&rft.epage=64-68&rft.eissn=0009-2614&rft.issn=0009-2614&rft.au=GALL%C3%89,%20Geoffrey&NICOUL,%20Matthieu&WOIKE,%20Theo&SCHANIEL,%20Dominik&FREYSZ,%20Eric&rft.genre=article |
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