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Copper Catalyst Activation Driven by Photoinduced Electron Transfer: A Prototype Photolatent Click Catalyst

hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorHARMAND, Lydie
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorCADET, Sarah
hal.structure.identifierInstitut Européen de Chimie et Biologie [IECB]
dc.contributor.authorKAUFFMANN, Brice
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorSCARPANTONIO, Luca
hal.structure.identifierLaboratoire Ondes et Matière d'Aquitaine [LOMA]
dc.contributor.authorBATAT, Pinar
hal.structure.identifierLaboratoire Ondes et Matière d'Aquitaine [LOMA]
dc.contributor.authorJONUSAUSKAS, Gediminas
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorMCCLENAGHAN, Nathan
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorLASTÉCOUÈRES, Dominique
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorVINCENT, Jean-Marc
dc.date.created2012-04-19
dc.date.issued2012
dc.identifier.issn1433-7851
dc.description.abstractEnWhile the copper(II) tren ketoprofenate precatalyst 1 is inactive at room temperature in methanol, it is quantitatively and rapidly reduced to its cuprous state upon light irradiation to provide a highly reactive click catalyst. By simply introducing air into the reaction medium the catalysis can be switched off and then switched on again by bubbling argon followed by irradiation.
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.rights.urihttp://creativecommons.org/licenses/by-nc-sa/
dc.subject.enphotolatent catalysts
dc.subject.enclick chemistry
dc.subject.encopper
dc.subject.enHuisgen cycloaddition
dc.subject.enphotocontrolled catalysts
dc.title.enCopper Catalyst Activation Driven by Photoinduced Electron Transfer: A Prototype Photolatent Click Catalyst
dc.typeArticle de revue
dc.identifier.doi10.1002/anie.201203014
dc.subject.halChimie/Catalyse
dc.subject.halChimie/Chimie de coordination
dc.subject.halPhysique [physics]/Physique [physics]/Chimie-Physique [physics.chem-ph]
bordeaux.journalAngewandte Chemie International Edition
bordeaux.page7137-7141
bordeaux.volume51
bordeaux.issue29
bordeaux.peerReviewedoui
hal.identifierhal-00731301
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00731301v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.date=2012&rft.volume=51&rft.issue=29&rft.spage=7137-7141&rft.epage=7137-7141&rft.eissn=1433-7851&rft.issn=1433-7851&rft.au=HARMAND,%20Lydie&CADET,%20Sarah&KAUFFMANN,%20Brice&SCARPANTONIO,%20Luca&BATAT,%20Pinar&rft.genre=article


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