Interaction entre résonance plasmon de surface et les propriétés de commutation dans des nanoparticules à base de nono-barreau d'or recouvert d'un composé à transition de spin
Language
en
Article de revue
This item was published in
Advanced Functional Materials. 2020-02-27, vol. 30, n° 17, p. 2000447 (9 p.)
Wiley
English Abstract
Rod-like gold nanoparticles are directly embedded in a 1D-polymeric spin crossover (SCO) material leading to singular Au@SCO nanohybridarchitectures. The resulting architectures are designed to promote a synergetic effect ...Read more >
Rod-like gold nanoparticles are directly embedded in a 1D-polymeric spin crossover (SCO) material leading to singular Au@SCO nanohybridarchitectures. The resulting architectures are designed to promote a synergetic effect between ultrafast spin-state photoswitching andphotothermal properties of plasmonic nanoparticles. This synergy is evidenced by the strong modulation of the surface plasmon resonance ofthe gold nanorods through the spin-state switching of the SCO component and also the strong enhancement of the photoswitching efficiency compared to pure SCO particles. This remarkable synergy results from the large modulation of the dielectric properties of the SCO polymer upon its thermal switching and the enhancement of the heating of these hybrid nanostructures upon excitation of the surface plasmon resonance of the gold nanorods.Read less <
ANR Project
Nanomatériaux hybrides pour une commutation photo-thermique contrôlée - ANR-17-CE09-0010
Origin
Hal imported