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hal.structure.identifierDepartment of Chemistry
hal.structure.identifierA. N. Nesmeyanov Institute of Organoelement Compounds [INEOS]
dc.contributor.authorFEDOROVA, Olga
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorLUKOVSKAYA, Elena
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorMIZEREV, Artem
hal.structure.identifierA. N. Nesmeyanov Institute of Organoelement Compounds [INEOS]
dc.contributor.authorFEDOROV, Yury
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorBOBYLYOVA, Alla
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorMAKSIMOV, Anton
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorMOISEEVA, Anna
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorANISIMOV, Aleksander
hal.structure.identifierCentre de physique moléculaire optique et hertzienne [CPMOH]
dc.contributor.authorJONUSAUSKAS, Gediminas
dc.date.created2009-03-16
dc.date.issued2010-03-01
dc.identifier.issn0894-3230
dc.description.abstractEnA novel ditopic receptor was constructed as a combination of bisthiophene with pyridinylvinyl and crown-containing styryl fragments. In the receptor, the pyridine residue was able to coordinate Fe2R, Cd2R, and Mg2R metal cations, whereas the oxocrown ether moiety bound with the alkaline earth metal (Mg2R, Ca2R, and Ba2R) cations. 1H NMR, optical, electrochemical, and ESI-MS results provided conclusive evidence of a complex formation through both the coordination centers of the molecule. The obtained results showed that cation complexation induces optical and electrochemical changes, particularly for each binding center. This type of multiparameter sensor provides interesting perspectives for the future design of unique sensors, promising different analytical techniques.
dc.language.isoen
dc.publisherWiley
dc.subject.enabsorption
dc.subject.encomplex
dc.subject.enditopic receptor
dc.subject.enelectrochemistry
dc.subject.enNMR spectroscopy
dc.title.enSynthesis and multiparameter sensor properties of the crown-containing thiophene derivatives
dc.typeArticle de revue
dc.identifier.doi10.1002/poc.1610
dc.subject.halPhysique [physics]/Physique [physics]/Chimie-Physique [physics.chem-ph]
bordeaux.journalJournal of Physical Organic Chemistry
bordeaux.page246-254
bordeaux.volume23
bordeaux.issue3
bordeaux.peerReviewedoui
hal.identifierhal-00505437
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00505437v1
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