Thermal diffusion in a binary liquid due to rectified molecular fluctuations
Langue
en
Article de revue
Ce document a été publié dans
Physical Review E : Statistical, Nonlinear, and Soft Matter Physics. 2011-03-18, vol. 83, n° 3, p. 030501 (4)
American Physical Society
Résumé en anglais
The Soret motion in binary liquids is shown to arise to a large extent from rectified velocity fluctuations. From a hard-bead model with elastic collisions in a nonuniform temperature, we derive a net force on each molecule, ...Lire la suite >
The Soret motion in binary liquids is shown to arise to a large extent from rectified velocity fluctuations. From a hard-bead model with elastic collisions in a nonuniform temperature, we derive a net force on each molecule, which is proportional to the temperature gradient and depends on the ratio of the molecular masses and moments of inertia. Our findings agree with previous numerical simulations and provide an explanation for the thermal diffusion isotope effect observed for several liquids.< Réduire
Mots clés en anglais
Soret effect
binary liquids
thermophoresis
Origine
Importé de halUnités de recherche