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hal.structure.identifierDepartment of Chemical and Biomolecular Engineering
hal.structure.identifierThe Smalley Institute for Nanoscale Science and Technology
hal.structure.identifierPhysical Chemistry and Applied Spectroscopy Group [C-PCS]
hal.structure.identifierCentre de physique moléculaire optique et hertzienne [CPMOH]
dc.contributor.authorDUQUE, Juan G.
hal.structure.identifierDepartment of Chemical and Biomolecular Engineering
hal.structure.identifierThe Smalley Institute for Nanoscale Science and Technology
hal.structure.identifierCentre de physique moléculaire optique et hertzienne [CPMOH]
dc.contributor.authorPARRA-VASQUEZ, A. Nicholas G.
hal.structure.identifierDepartment of Chemical and Biomolecular Engineering
hal.structure.identifierThe Smalley Institute for Nanoscale Science and Technology
dc.contributor.authorBEHABTU, Natnael
hal.structure.identifierDepartment of Chemical and Biomolecular Engineering
hal.structure.identifierThe Smalley Institute for Nanoscale Science and Technology
hal.structure.identifierPhysical Chemistry and Applied Spectroscopy Group [C-PCS]
dc.contributor.authorGREEN MICAH, J.
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorHIGGINBOTHAM, Amanda L.
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorPRICE, B. Katherine
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorLEORNARD, Ashley D.
hal.structure.identifierDepartment of Chemical and Biomolecular Engineering
hal.structure.identifierThe Smalley Institute for Nanoscale Science and Technology
hal.structure.identifierSaudi Aramco
dc.contributor.authorSCHMIDT, Howard K.
hal.structure.identifierCentre de physique moléculaire optique et hertzienne [CPMOH]
dc.contributor.authorLOUNIS, Brahim
hal.structure.identifierThe Smalley Institute for Nanoscale Science and Technology
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorTOUR, James M.
hal.structure.identifierPhysical Chemistry and Applied Spectroscopy Group [C-PCS]
dc.contributor.authorDOORN, Stephen K.
hal.structure.identifierCentre de physique moléculaire optique et hertzienne [CPMOH]
dc.contributor.authorCOGNET, Laurent
hal.structure.identifierDepartment of Chemical and Biomolecular Engineering
hal.structure.identifierThe Smalley Institute for Nanoscale Science and Technology
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorPASQUALI, Matteo
dc.date.created2010-01-27
dc.date.issued2010-06-22
dc.identifier.issn1936-0851
dc.description.abstractEnWe study the solubility and dispersibility of as-produced and purified HiPco single-walled carbon nanotubes (SWNTs). Variation in specific operating conditions of the HiPco process are found to lead to significant differences in the respective SWNT solubilities in oleum and surfactant suspensions. The diameter distributions of SWNTs dispersed in surfactant solutions are batch-dependent, as evidenced by luminescence and Raman spectroscopies, but are identical for metallic and semiconducting SWNTs within a batch. We thus find that small diameter SWNTs disperse at higher concentration in aqueous surfactants and dissolve at higher concentration in oleum than do large-diameter SWNTs. These results highlight the importance of controlling SWNT synthesis methods in order to optimize processes dependent on solubility, including macroscopic processing such as fiber spinning, material reinforcement, and films production, as well as for fundamental research in type selective chemistry, optoelectronics, and nanophotonics.
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.subject.ensingle-walled carbon nanotubes
dc.subject.ensolubility
dc.subject.ensolutions
dc.subject.endispersions
dc.subject.endiameter
dc.title.enDiameter-Dependent Solubility of Single-Walled Carbon Nanotubes
dc.typeArticle de revue
dc.identifier.doi10.1021/nn100170f
bordeaux.journalACS Nano
bordeaux.page3063-3072
bordeaux.volume4
bordeaux.issue6
bordeaux.peerReviewedoui
hal.identifierhal-00609610
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00609610v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=ACS%20Nano&rft.date=2010-06-22&rft.volume=4&rft.issue=6&rft.spage=3063-3072&rft.epage=3063-3072&rft.eissn=1936-0851&rft.issn=1936-0851&rft.au=DUQUE,%20Juan%20G.&PARRA-VASQUEZ,%20A.%20Nicholas%20G.&BEHABTU,%20Natnael&GREEN%20MICAH,%20J.&HIGGINBOTHAM,%20Amanda%20L.&rft.genre=article


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