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hal.structure.identifierA. N. Nesmeyanov Institute of Organoelement Compounds [INEOS]
dc.contributor.authorFEDOROV, Yuri V.
hal.structure.identifierA. N. Nesmeyanov Institute of Organoelement Compounds [INEOS]
dc.contributor.authorSHEPEL, N. E.
hal.structure.identifierA. N. Nesmeyanov Institute of Organoelement Compounds [INEOS]
dc.contributor.authorCHERNIKOVA, Ekaterina Yu.
hal.structure.identifierA. N. Nesmeyanov Institute of Organoelement Compounds [INEOS]
dc.contributor.authorFEDOROVA, Olga A.
hal.structure.identifierA. N. Nesmeyanov Institute of Organoelement Compounds [INEOS]
dc.contributor.authorGULAKOVA, Elena N.
hal.structure.identifierPhotochemistry Center
dc.contributor.authorAVAKYAN, V. G.
hal.structure.identifierCentre de physique moléculaire optique et hertzienne [CPMOH]
dc.contributor.authorJONUSAUSKAS, Gediminas
dc.date.created2008-04-30
dc.date.issued2008-11-18
dc.identifier.issn1066-5285
dc.description.abstractEnThe reversible photochemical E--Z-isomerization of crown-containing 4-styrylpyridine was studied. The reaction was carried out in the presence of alkaline-earth metals capable of forming complexes with the crown-ether fragment and heavy metal perchlorates (Hg2+, Cd2+) that are able to coordinate the nitrogen atom of the heterocyclic residue. The influence of complex formation on the E--Z-photoisomerization was determined by electronic spectroscopy and 1H NMR spectroscopy. The studies performed confirm that the E--Z-photoisomerization can be controlled using supramolecular complex formation.
dc.language.isoen
dc.publisherSpringer Verlag
dc.subject.enmercury perchlorate
dc.subject.en15-crown-5 ethe
dc.subject.encrown-containing styrylpyridine
dc.subject.enE--Z-photoisomerization
dc.subject.encomplex formation
dc.subject.enalkaline-earth metal perchlorates
dc.subject.encadmium perchlorate
dc.subject.enmercury perchlorate.
dc.title.enSpecific features of reversible E--Z-photoisomerization of crown-containing 4-styrylpyridine complexes with various cations
dc.typeArticle de revue
dc.identifier.doi10.1007/s11172-008-0340-0
dc.subject.halPhysique [physics]/Physique [physics]/Chimie-Physique [physics.chem-ph]
bordeaux.journalRussian Chemical Bulletin
bordeaux.page2385-2393
bordeaux.volume57
bordeaux.issue11
bordeaux.peerReviewedoui
hal.identifierhal-00747017
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00747017v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Russian%20Chemical%20Bulletin&rft.date=2008-11-18&rft.volume=57&rft.issue=11&rft.spage=2385-2393&rft.epage=2385-2393&rft.eissn=1066-5285&rft.issn=1066-5285&rft.au=FEDOROV,%20Yuri%20V.&SHEPEL,%20N.%20E.&CHERNIKOVA,%20Ekaterina%20Yu.&FEDOROVA,%20Olga%20A.&GULAKOVA,%20Elena%20N.&rft.genre=article


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