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Mechanochromic luminescence of copper iodide clusters.

hal.structure.identifierLaboratoire de physique de la matière condensée [LPMC]
dc.contributor.authorBENITO, Quentin
hal.structure.identifierLaboratoire de physique de la matière condensée [LPMC]
dc.contributor.authorMAURIN, Isabelle
hal.structure.identifierLaboratoire Hétéroéléments et Coordination [DCPH]
dc.contributor.authorCHEISSON, Thibaut
hal.structure.identifierLaboratoire Hétéroéléments et Coordination [DCPH]
dc.contributor.authorNOCTON, Gregory
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorFARGUES, Alexandre
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGARCIA, Alain
hal.structure.identifierInstitut Lavoisier de Versailles [ILV]
dc.contributor.authorMARTINEAU, Charlotte
hal.structure.identifierLaboratoire de physique de la matière condensée [LPMC]
dc.contributor.authorGACOIN, Thierry
hal.structure.identifierLaboratoire de physique de la matière condensée [LPMC]
dc.contributor.authorBOILOT, Jean-Pierre
hal.structure.identifierLaboratoire de physique de la matière condensée [LPMC]
dc.contributor.authorPERRUCHAS, Sandrine
dc.date.issued2015
dc.identifier.issn0947-6539
dc.description.abstractEnLuminescent mechanochromic materials are particularly appealing for the development of stimuli-responsive materials. Establishing the mechanism responsible for the mechanochromism is always an issue owing to the difficulty in characterizing the ground phase. Herein, the study of real crystalline polymorphs of a mechanochromic and thermochromic luminescent copper iodide cluster permits us to clearly establish the mechanism involved. The local disruption of the crystal packing induces changes in the cluster geometry and in particular the modification of the cuprophilic interactions, which consequently modify the emissive states. This study constitutes a step further toward the understanding of the mechanism involved in the mechanochromic luminescent properties of multimetallic coordination complexes.
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.title.enMechanochromic luminescence of copper iodide clusters.
dc.typeArticle de revue
dc.identifier.doi10.1002/chem.201500251
dc.subject.halChimie/Matériaux
bordeaux.journalChemistry - A European Journal
bordeaux.page5892-5897
bordeaux.volume21
bordeaux.issue15
bordeaux.peerReviewedoui
hal.identifierhal-01137300
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01137300v1
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