A tris(triazolate) ligand for a highly active and magnetically recoverable palladium catalyst of selective alcohol oxidation using air at atmospheric pressure
| hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
| dc.contributor.author | WANG, Dong | |
| hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
| dc.contributor.author | DERAEDT, Christophe | |
| hal.structure.identifier | Laboratoire de chimie de coordination [LCC] | |
| dc.contributor.author | SALMON, Lionel | |
| hal.structure.identifier | Plateforme Aquitaine de Caractérisation des Matériaux [PLACAMAT] | |
| dc.contributor.author | LABRUGÈRE, Christine | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | ETIENNE, Laetitia | |
| hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
| dc.contributor.author | RUIZ, Jaime | |
| hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
| dc.contributor.author | ASTRUC, Didier | |
| dc.date.issued | 2015 | |
| dc.identifier.issn | 0947-6539 | |
| dc.description.abstractEn | High efficiency and selectivity, easy magnetic recovery and recycling, and use of air as the oxidant at atmospheric pressure are major objectives for oxidation catalysis in terms of sustainable and green processes. A tris(triazolyl) ligand, so far only used in copper-catalyzed alkyne azide cycloadditions, was found to be extremely efficient in SiO2 /γ-Fe2 O3 -immobilized palladium complexes. It was characterized by inductively coupled plasma (ICP) analysis, transmission electron microscopy (TEM), scanning transmission electron microscopy (STEM), energy-dispersive X-ray spectroscopy (EDX), and X-ray photoelectron spectra (XPS) and found to fulfill the combined conditions for the selective oxidation of alcohols to aldehydes and ketones. | |
| dc.language.iso | en | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.subject.en | Alcohols | |
| dc.subject.en | Heterogeneous catalysis | |
| dc.subject.en | Magnetic properties | |
| dc.subject.en | Oxidation | |
| dc.subject.en | Palladium | |
| dc.title.en | A tris(triazolate) ligand for a highly active and magnetically recoverable palladium catalyst of selective alcohol oxidation using air at atmospheric pressure | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1002/chem.201500122 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Chemistry - A European Journal | |
| bordeaux.page | 6501-6510 | |
| bordeaux.volume | 21 | |
| bordeaux.issue | 17 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01141701 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01141701v1 | |
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