A tris(triazolate) ligand for a highly active and magnetically recoverable palladium catalyst of selective alcohol oxidation using air at atmospheric pressure
Idioma
en
Article de revue
Este ítem está publicado en
Chemistry - A European Journal. 2015, vol. 21, n° 17, p. 6501-6510
Wiley-VCH Verlag
Resumen en inglés
High efficiency and selectivity, easy magnetic recovery and recycling, and use of air as the oxidant at atmospheric pressure are major objectives for oxidation catalysis in terms of sustainable and green processes. A ...Leer más >
High efficiency and selectivity, easy magnetic recovery and recycling, and use of air as the oxidant at atmospheric pressure are major objectives for oxidation catalysis in terms of sustainable and green processes. A tris(triazolyl) ligand, so far only used in copper-catalyzed alkyne azide cycloadditions, was found to be extremely efficient in SiO2 /γ-Fe2 O3 -immobilized palladium complexes. It was characterized by inductively coupled plasma (ICP) analysis, transmission electron microscopy (TEM), scanning transmission electron microscopy (STEM), energy-dispersive X-ray spectroscopy (EDX), and X-ray photoelectron spectra (XPS) and found to fulfill the combined conditions for the selective oxidation of alcohols to aldehydes and ketones.< Leer menos
Palabras clave en inglés
Alcohols
Heterogeneous catalysis
Magnetic properties
Oxidation
Palladium
Orígen
Importado de HalCentros de investigación