DOUSSINEAU, Tristan; DÉSERT, Anthony; LAMBERT, Olivier; TAVEAU, Jean-Christophe; LANSALOT, Muriel; DUGOURD, Philippe; BOURGEAT-LAMI, Elodie; RAVAINE, Serge; DUGUET, Etienne; ANTOINE, Rodolphe

doi:10.1021/jp510081v

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DOUSSINEAU, Tristan
Institut Lumière Matière [Villeurbanne] [ILM]

DÉSERT, Anthony
Chimie et Biologie des Membranes et des Nanoobjets [CBMN]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

LAMBERT, Olivier
Chimie et Biologie des Membranes et des Nanoobjets [CBMN]

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Article de revue

Ce document a été publié dans

Journal of Physical Chemistry C. 2015, vol. 119, n° 20, p. 10844-10849

American Chemical Society

Résumé en anglais

Binary colloidal particles of polyhedral morphology, obtained by an emulsion polymerization of styrene in the presence of silica seeds, are studied. Because of kinetic effects, composite particles usually exhibit polydispersity in size, shape, and composition. Thus, accurate techniques aiming at characterizing the size and the shape, as well as the composition and surface properties of such objects, are required. In this work, we use charge detection mass spectrometry (CD-MS) as a tool for the characterization of nanometer-sized composite (clusters of) particles. CD-MS measures both the mass and the charge for each ion. This single ion mass spectrometry technique enables one to construct a histogram of mass, yielding the mass distribution. CD-MS for molar mass determination and composition of composite particles is demonstrated to be complementary to transmission electron microscopy. The study of the charging capacity of these composite particles in the gas phase also appears as a valuable approach to probe the surface area of such complex nano-objects, thus giving some insight about their structure and morphology.< Réduire

DOI

http://dx.doi.org/10.1021/jp510081v

Project ANR

Emissive properties of nanohybrids in vacuo and in droplets. A bottom-up approach of the metal-organic Interface
Développement d'un Nouvel Outil de Nanométrologie Polyscopique Couplant Spectrométrie de Masse et Spectroscopie Laser - ANR-11-PDOC-0032

Origine

Importé de hal

Unités de recherche

Institut de Chimie de la Matière Condensée de Bordeaux (ICMCB) - UMR 5026