Direct C−N Coupling in an in Situ Ligand Transformation and the Self-Assembly of a Tetrametallic [NiII4] Staircase
| hal.structure.identifier | Department of Chemistry, Indian Institute of Technology | |
| dc.contributor.author | GHOSH, Aloke Kumar | |
| dc.contributor.author | MAHAPATRA, Tufan Singha | |
| hal.structure.identifier | Centre de recherches Paul Pascal [CRPP] | |
| dc.contributor.author | CLÉRAC, Rodolphe | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | MATHONIÈRE, Corine | |
| hal.structure.identifier | Dipartemento di Science Chimiche e Farmaceutiche | |
| dc.contributor.author | BERTOLASI, Valerio | |
| hal.structure.identifier | Department of Chemistry, Indian Institute of Technology | |
| dc.contributor.author | RAY, Debashis | |
| dc.date.issued | 2015-05-18 | |
| dc.identifier.issn | 0020-1669 | |
| dc.description.abstractEn | A [NiII4] staircase complex was serendipitously prepared from the reaction of the binucleating Schiff base proligand 2,6-bis[[(3-hydroxypropyl)imino]-methyl]-4-methylphenol (H3L2) and 3,5-dimethylpyrazole (Me2pzH) with nickel(II) nitrate in a reaction at room temperature, initially aimed to yield a dinuclear complex. From a room temperature metal ion/ligand reaction, the proligand H3L2 in situ transformed to modified formsHL32− and HL42−, allowing the [Ni4] formation. Variable temperature magnetic behavior of a [Ni4] complex reveals antiferromagnetic interactions with stabilization of a diamagnetic ground state (ST = 0). | |
| dc.language.iso | en | |
| dc.publisher | American Chemical Society | |
| dc.title.en | Direct C−N Coupling in an in Situ Ligand Transformation and the Self-Assembly of a Tetrametallic [NiII4] Staircase | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1021/acs.inorgchem.5b00411 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Inorganic Chemistry | |
| bordeaux.page | 5136-5138 | |
| bordeaux.volume | 54 | |
| bordeaux.issue | 11 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01161910 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01161910v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Inorganic%20Chemistry&rft.date=2015-05-18&rft.volume=54&rft.issue=11&rft.spage=5136-5138&rft.epage=5136-5138&rft.eissn=0020-1669&rft.issn=0020-1669&rft.au=GHOSH,%20Aloke%20Kumar&MAHAPATRA,%20Tufan%20Singha&CL%C3%89RAC,%20Rodolphe&MATHONI%C3%88RE,%20Corine&BERTOLASI,%20Valerio&rft.genre=article |
Fichier(s) constituant ce document
| Fichiers | Taille | Format | Vue |
|---|---|---|---|
|
Il n'y a pas de fichiers associés à ce document. |
|||