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Insertion of a [FeII(pyimH)3]2+ [pyimH = 2-(1H-Imidazol-2-yl)pyridine] Spin-Crossover Complex Inside a Ferromagnetic Lattice Based on a Chiral 3D Bimetallic Oxalate Network
| hal.structure.identifier | Instituto de Ciencia Molecular [ICMol] | |
| dc.contributor.author | LÓPEZ-JORDÀ, Maurici | |
| hal.structure.identifier | Instituto de Ciencia Molecular [ICMol] | |
| dc.contributor.author | GIMÉNEZ-MARQUÉS, Mónica | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | DESPLANCHES, Cédric | |
| hal.structure.identifier | Instituto de Ciencia Molecular [ICMol] | |
| dc.contributor.author | MÍNGUEZ ESPALLARGAS, Guillermo | |
| hal.structure.identifier | Instituto de Ciencia Molecular [ICMol] | |
| dc.contributor.author | CLEMENTE-LEÓN, Miguel | |
| dc.date.issued | 2016 | |
| dc.identifier.issn | 1434-1948 | |
| dc.description.abstractEn | The insertion of the [FeII(pyimH)3]2+ [pyimH = 2-(1H-imidazol-2-yl)pyridine] spin-crossover complex into a ferromagnetic bimetallic oxalate network affords the hybrid compound [FeII(pyimH)3][MnIICrIII(ox)3]2·X (ox = C2O42–). This spin-crossover complex templates the growth of crystals formed by a chiral 3D oxalate network. The magnetic properties of this hybrid magnet show the coexistence of long-range ferromagnetic ordering at 4.5 K and a spin crossover of the intercalated [FeII(pyimH)3]2+ complex above 250 K. The compound presents a light-induced excited spin-state trapping (LIESST) effect below 60 K although with limited photoconversion (less than 8 %). | |
| dc.language.iso | en | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.subject.en | Spin crossover | |
| dc.subject.en | Magnetic properties | |
| dc.subject.en | Chirality | |
| dc.subject.en | Iron | |
| dc.subject.en | Oxalates | |
| dc.title.en | Insertion of a [FeII(pyimH)3]2+ [pyimH = 2-(1H-Imidazol-2-yl)pyridine] Spin-Crossover Complex Inside a Ferromagnetic Lattice Based on a Chiral 3D Bimetallic Oxalate Network | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1002/ejic.201500790 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | European Journal of Inorganic Chemistry | |
| bordeaux.page | 2187–2192 | |
| bordeaux.issue | 13-14 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01315419 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01315419v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=European%20Journal%20of%20Inorganic%20Chemistry&rft.date=2016&rft.issue=13-14&rft.spage=2187%E2%80%932192&rft.epage=2187%E2%80%932192&rft.eissn=1434-1948&rft.issn=1434-1948&rft.au=L%C3%93PEZ-JORD%C3%80,%20Maurici&GIM%C3%89NEZ-MARQU%C3%89S,%20M%C3%B3nica&DESPLANCHES,%20C%C3%A9dric&M%C3%8DNGUEZ%20ESPALLARGAS,%20Guillermo&CLEMENTE-LE%C3%9&rft.genre=article |
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