Influence of hydrogenation and mechanical grinding on the structural and ferromagnetic properties of GdFeSi
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en
Article de revue
Este ítem está publicado en
Zeitschrift fur Naturforschung B. 2016-01, vol. 71, n° 5, p. 419-424
Verlag der Zeitschrift Fuer Naturforschung
Resumen en inglés
Hydrogen insertion into GdFeSi induces (i) a structural transition from a tetragonal CeFeSi-type to a tetragonal ZrCuSiAs-type, (ii) an anisotropic expansion of the unit cell parameters because the a parameter decreases, ...Leer más >
Hydrogen insertion into GdFeSi induces (i) a structural transition from a tetragonal CeFeSi-type to a tetragonal ZrCuSiAs-type, (ii) an anisotropic expansion of the unit cell parameters because the a parameter decreases, whereas the c parameter increases, and (iii) a decrease in Curie temperature from 121 to 20 K. On the contrary, an amorphous ferromagnet (TC = 65 K) is obtained by mechanical grinding of GdFeSi. The three compounds (GdFeSi, GdFeSiH, and amorphous GdFeSi) were investigated by 57Fe Mössbauer spectroscopy. At 4.2 K, this study has revealed that the magnetically ordered Gd substructure produces a small transferred hyperfine magnetic field at the 57Fe nucleus.< Leer menos
Palabras clave en inglés
hydrogenation
magnetization
mechanical grinding
Mössbauer spectroscopy
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