Cerium intermetallics with TiNiSi-type structure
Language
en
Article de revue
This item was published in
Zeitschrift fur Naturforschung B. 2016-01, vol. 71, n° 7, p. 737-764
Verlag der Zeitschrift Fuer Naturforschung
English Abstract
Intermetallic compounds with the equiatomiccomposition CeTX that crystallize with the orthorhombicTiNiSi-type structure can be synthesized with electronrichtransition metals (T) and X = Zn, Al, Ga, Si, Ge, Sn,As, Sb, and ...Read more >
Intermetallic compounds with the equiatomiccomposition CeTX that crystallize with the orthorhombicTiNiSi-type structure can be synthesized with electronrichtransition metals (T) and X = Zn, Al, Ga, Si, Ge, Sn,As, Sb, and Bi. The present review focusses on the crystalchemistry and chemical bonding of these CeTX phasesand on their physical properties, 119Sn and 121Sb Mössbauerspectra, high-pressure effects, hydrogenation reactionsand the formation of solid solutions in order to elucidatestructure–property relationships. This paper is the finalone of a series of four reviews on equiatomic intermetalliccerium compoundsRead less <
English Keywords
cerium compounds
crystal structure
intermetallics
physical properties
structure–property relationship
Origin
Hal imported