Organic-inorganic hybrid perovskite (C6H5(CH2)2NH3)2CdCl4: Synthesis, structural and thermal properties
| hal.structure.identifier | Laboratoire de Physique des Matériaux et Modélisation des Systèmes [LP2MS] | |
| dc.contributor.author | KASSOU, Said | |
| hal.structure.identifier | Physic Department | |
| dc.contributor.author | KAIBA, Abdellah | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | GUIONNEAU, Philippe | |
| hal.structure.identifier | Laboratoire de Physique des Matériaux et Modélisation des Systèmes [LP2MS] | |
| dc.contributor.author | BELAARJ, Abdesselam | |
| dc.date.issued | 2016 | |
| dc.identifier.issn | 0022-4766 | |
| dc.description.abstractEn | The present research work reports the study on crystal structure, vibrational spectroscopy and thermal analysis of organic-inorganic hybrid compound (C6H5(CH2)2NH3)2CdCl4. Single crystals of bis(phenethylammonium)tetrachlorocadmate (C6H5(CH2)2NH3)2CdCl4 (PEA–Cd) were obtained by diffusion at room temperature. This compound crystallizes in the orthorhombic space group C2cb with unit cell parameters a = 7.4444(2) Å, b = 38.8965(3) Å, c = 7.3737(2) Å and Z = 4. Single crystal structure has been solved and refined to R = 0.036 and wR = 0.092. The structure consists of an extended [CdCl4]2– network and two [C6H5(CH2)2NH3]+ cations to form a two-dimensional perovskite system. The infrared (IR) spectrum of the title compound was recorded at room temperature. Differential scanning calorimetry (DSC) was used to investigate the phase transition; this compound exhibits a reversible single solid-solid phase transition. | |
| dc.language.iso | en | |
| dc.publisher | Springer Verlag (Germany) | |
| dc.subject.en | layered perovskite | |
| dc.subject.en | organic-inorganic hybrid | |
| dc.subject.en | structural phase transition | |
| dc.subject.en | single crystal | |
| dc.subject.en | differential scanning calorimetry (DSC) | |
| dc.title.en | Organic-inorganic hybrid perovskite (C6H5(CH2)2NH3)2CdCl4: Synthesis, structural and thermal properties | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1134/S0022476616040168 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Journal of Structural Chemistry | |
| bordeaux.page | 737-743 | |
| bordeaux.volume | 57 | |
| bordeaux.issue | 4 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01395057 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01395057v1 | |
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