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Solubility of inorganic salts in sub- and supercritical hydrothermal environment: Application to SCWO processes

hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorVOISIN, Thomas
hal.structure.identifierInstitut de Mécanique et d'Ingénierie de Bordeaux [I2M]
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorERRIGUIBLE, Arnaud
hal.structure.identifierINNOVEOX
dc.contributor.authorBALLENGHIEN, David
hal.structure.identifierINNOVEOX
dc.contributor.authorMATEOS, David
hal.structure.identifierAgence de l'Environnement et de la Maîtrise de l'Energie [ADEME]
dc.contributor.authorKUNEGEL, André
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCANSELL, François
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorAYMONIER, Cyril
dc.date.issued2017
dc.identifier.issn0896-8446
dc.description.abstractEnSupercritical water oxidation process (SCWO) is of great interest today in recycling toxic and/or complexed chemical wastes with very good efficiency. When reaching the critical conditions (374 °C, 22.1 MPa), polarity collapses and water becomes a very good solvent for organic compounds. However, these interesting properties for organics turn to be problematic regarding dissolved inorganics. Commonly present in the aqueous waste, those inorganics precipitate easily when approaching the critical domain, leading to plugs in the process. In order to better understand the precipitation of salts in supercritical water, their solubility behaviour is of main interest. However, lots of relevant data are still missing in the literature. The aim of this review is to summarise most of the existing data regarding salt solubility in sub- and supercritical water as well as the different set-ups and methods developed over the past 50 years, including predictive theoretical modelling.
dc.language.isoen
dc.publisherElsevier
dc.subject.enSupercritical water
dc.subject.enSupercritical water oxidation
dc.subject.enInorganic salts
dc.subject.enSalt solubility
dc.subject.enPrecipitation
dc.title.enSolubility of inorganic salts in sub- and supercritical hydrothermal environment: Application to SCWO processes
dc.typeArticle de revue
dc.identifier.doi10.1016/j.supflu.2016.09.020
dc.subject.halChimie/Matériaux
dc.subject.halSciences de l'environnement/Ingénierie de l'environnement
bordeaux.journalJournal of Supercritical Fluids
bordeaux.page18-31
bordeaux.volume120, Part 1
bordeaux.peerReviewedoui
hal.identifierhal-01417006
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01417006v1
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