Optically switchable behaviour of a dioxolene adduct of a cobalt-macrocycle complex
Language
en
Article de revue
This item was published in
Chemical Physics Letters. 2004, vol. 396, n° 1-3, p. 198-201
Elsevier
English Abstract
Reflectivity and magnetic measurements show that Co(CTH)(Phendiox)]PF6 · H2O (CTH = DL-5,7,7,12,14,14-9,10-hexamethyl-1,4,8,11-tetraazacyclotetradecane and Phendiox = semiquinonato or catecholato forms of 9,10-dioxophenantherene) ...Read more >
Reflectivity and magnetic measurements show that Co(CTH)(Phendiox)]PF6 · H2O (CTH = DL-5,7,7,12,14,14-9,10-hexamethyl-1,4,8,11-tetraazacyclotetradecane and Phendiox = semiquinonato or catecholato forms of 9,10-dioxophenantherene) undergoes valence tautomeric interconversion cobalt(III)–catecholato to cobalt(II)–semiquinonato upon light irradiation...Read less <
English Keywords
Hexamethyl tetraazacyclotetradecane
Dioxophenanthrene
Alkane
Alkene
Cobalt complex
Macrocyclic compound
Origin
Hal imported